Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/16414
標題: 利用核磁共振光譜儀及X-光單晶繞射儀探討金屬大環錯化合物,M(Por)(L)n之分子結構,其中M =鉈、鎳,Por = (N-NCOCH=CHC6H5-tpp)
Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Tl and Ni , Por = (N-NCOCH=CHC6H5-tpp)
作者: 劉偉欽
Liu, Wei-Chin
關鍵字: NMR Spectroscopy;核磁共振光譜儀;X-Ray Single-Crystal;Ni;光單晶繞射儀;鎳
出版社: 化學系所
引用: 參考文獻 1. H. J. Callot, B. Chevrier and R. Weiss, J. Am. Chem. Soc., 1978, 100, 4733. 2. J. Y. Tung, J. I. Jang, C. C. Lin, J. H. Chen and L. P. Hwang, Inorg. Chem., 2000, 39, 1106. 3. Y. I. Li, C. S. Chang, J. Y. Tung, C. H. Tsai, J. H. Chen, F. L. Liao and S. L. Wang, Polyhedron, 2000, 19, 413. 1. H. J. Callot, B. Chevrier and R. Weiss, J. Am. Chem. Soc., 1978, 100, 4733. 2. J. Y. Tung, J. I. Jang, C. C. Lin, J. H. Chen and L. P. Hwang, Inorg. Chem., 2000, 39, 1106. 3. Y. I. Li, C. S. Chang, J. Y. Tung, C. H. Tsai, J. H. Chen, F. L. Liao and S. L. Wang, Polyhedron, 2000, 19, 413. 4. C. S. Chang, C. H. Chen, Y. I. Li, B. C. Liau, B. T. Ko, S. Elango and J. H. Chen, Inorg. Chem., 2001, 40, 2905. 5. A. W. Addison, T. N. Rao, J. Reedijk, J. V. Rijn and G. C. Verchoor, J. Chem. Soc., Dalton Trans., 1984, 1349. 6. R. G. Garvey, R. O. Koob and M. L. Morris, Acta Crystallogr., Sect.C, 1987, 43, 2056.
摘要: 
⤀26;⤟76;⤆41;⤏05;⤕50;我們將大環(N-NCO-HC=CH-C6H5-tpp)溶於CH2Cl2中,再加入 Ni(OAc)2 和其反應形成金屬錯化合物,藉由 1H-1H COSY、HSQC、HMBC 及DEPT 等核磁共振光譜來分析,並用X-ray單晶繞射儀鑑定其結構,並比較其差異。⣺78;
URI: http://hdl.handle.net/11455/16414
其他識別: U0005-0307200616062800
Appears in Collections:化學系所

Show full item record
 

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.