Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/16489
標題: 利用核磁共振光譜儀及X-ray單晶繞射儀探討金屬大環錯合物 M(por)(L)n之分子結構,其中M1 = 鉈,por1 = N-NCO-HC=CH-C6H5-tpp;M2 = 鎘,por2 = N-NHCO-C4H3O-tpp
Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-ray Single-Crystal Determination on Metalloporphyrin : M(por)(L)n, M1 = Tl,por1 = N-NCO-HC=CH-C6H5-tpp;M2 = Cd, por2 = N-NHCO-C4H3O-tpp
作者: 郭智維
Guo, Chih-Wei
關鍵字: Metalloporphyrin;金屬大環
出版社: 化學系所
引用: 1. Omura. T.; Sato, R. J. Biol. Chem. 1994, 239, 2370. 2. Dolphin, D., Ed The Porphyrins; New York, 1978. 3. Dolphin, D., B12;. Wiley: New York, 1982. 4. D''Souza, F.; Smith, P. M.; Zandler, M. E.; McCarty, A. L.; Itou, M.; Araki, Y.; Ito, O. J. Am. Chem. Soc. 2004, 126, 7898. 5. Abrahams, B. F.; Hoskins, B. F.; Michall, D. M.; Robson, R. Nature 1994, 369, 727. 6. Bonnett, R.; White, R. D.; Winfield, U.-J.; Berenbaum, M. C. Biochem. J. 1989, 261, 277. 7. Goh, Y. M.; Nam, W. Inorg. Chem. 1999, 38, 914. 8. Mazzanti, M.; Marchon, J.-C.; Shang, M.; Scheidt, W. R.; Jia, S.; Shelnutt, J. A. J. Am. Chem. Soc. 1997, 119, 12400. 9. Adler, A. D.; Longo, F. R.; Finarelli, J. D.; Goldmacher, J.; Assour, J; Korsakoff, L. J. Org. Chem. 1967, 32, 476. 10. Lindsey, J. S.; Schreiman, I. C.; Hsu, H. C.; Kearney, P. C.; Marguerettaz, A. M. J. Org. Chem. 1987, 52, 827. 11. Arsenault, G. P.; Bullock, E.; MacDonald, S. F. J. Am. Chem. Soc. 1960, 82, 4384. 12. Boudif, A.; Momenteau, M. J. Chem. Soc., Chem. Commun. 1994, 2069. 13. Boudif, A.; Momenteau, M. J. Chem. Soc., Perkin Trans 1 1996, 1235. 14. Sn(tpp)(ClO4)2: Lee, W. B.; Suen, S. C.; Hong, F. E.; Chen, J. H.; Jong, T. T.; Hwang, L. P. Journal of the Cinese Chemical Society 1992, 39, 143 Tl(p-Cl)4(OAc); In(p-X)4(OAc) X = Br, Cl: Lee, Y. Y.; Chen, J. H.; Hsieh, H. Y. Polyhedron 2003, 22, 1633 - 1639. Tl(TPyP)CN: Chen, T. W.; Chen, J. H.; Hong, F. E.; Wang, S. L.; Hwang, L. P. Polyhedron 1994, 13, 403. Tl(p-Cl)4(O2CCF3); Tl(p-Cl)4(O2CCF2CF3): Lee, Y. Y.; Chen, J. H.; Hsieh, H. Y.; Liau, B. C.; Liao, F. L.; Wang, S. L.; Elango, S. Inorg. Chem. Commun. 2003, 6, 252 - 258. 15. Callot, H. J.; Chevrier, B.; Weiss, R. J. Am. Chem. Soc. 1978, 100, 4133. 16. Ichimura. K. Chem. Lett. 1976, 641. 17. Ernst, L. J. Organomet. Chem. 1974, 82, 319. Ernst, L. Organiac Magnetic Resonance 1974, 6, 540. 18. Kitching, W.; Praeger, D.; Moore, C. J.; Doddrell, D; Adcock, W. J. Organomet. Chem. 1974, 70, 339. Kitching, W.; Moore, C. J.; Doddrell, D.; Adcock, W. J. Organomet. Chem. 1975, 71, 469. 19. Moy, S. A.; Gonzalez, J. A.; Wilson, L. J. Acta. Cryst. 1995, C51, 1490. 20. Chen, J. C.; Jang, H. S.; Chen, H. J.; Hwang, L. P. Polyhedron 1991, 10, 2069. 21. Suen, S. C.; Lee, W. B.; Hong, F. E.; Jong, T. T.; Chen, J. C.; Chen, H. J.; Hwang, L. P. Polyhedron 1992, 11, 3025. 22. Chou, L. F.; Chen, J. H. J. Chem. Soc., Dalton Trans. 1996, 3787 - 3792. 23. Shil, W. Z.; Cho, K. Y.; Cheng, C. W.; Chen, J. H.; Wang, S. S.; Liao, F. L.; Tung, J. Y.; Hsieh, H. Y.; Elango, S. Polyhedron 2006, 25, 1864 – 1872. 24. 彭正吉 2005.06 中興大學化學系碩士學位論文:利用核磁共振光譜儀及X-ray單晶繞射儀探討金屬大環錯化合物,M(por)(L)n之分子結構,其中M = 鉈、鋅、鎳,por = (N-NCOC4H3S)。 25. Pearson, R. G. Inorg. Chem. 1988, 27, 734. 26. Huheey, J. E.; Keiter, E. A.; Keiter, R. L. Inorganic Chemistry, Harper Collins College Publishers, New York, 4th edn., 1993, pp114, 292. 27.Fundo, M.; Sousa, A.; Bermejo, M. R.;Gaorcia-Deibe, A.; Sousa- Pedrares, A.; Hoyos O. L.; Helliawall, M. Eur. J. Inorg. Chem., 2002, 703.
摘要: 
本實驗室乃利用 H. J. Callot 所使用之金屬光化學合成策略,將acyl azide 與Zntpp, meso-tetraphenylporphyrinatozinc(II) 反應,合成N-substituted porphyrin: N-cinnamamido-meso-tetraphenylporphyrin, (N-NHCO-HC=CH- C6H5-Htpp), 4。此大環 (free base) 利用金屬鹽類-三氟醋酸鉈 [Tl(O2CCF3)]與之反應,合成trifluoroacetato N-cinnamimido-meso-tetraphenyl- porphyrinatothallium(III),Tl(N-NCO-HC=CH-C6H5-tpp)(O2CCF3) (5) 錯合物,並解出其X-ray單晶晶體結構,得知空間對稱群為C2/c。除此之外更進一步地利用核磁共振光譜鑑定其結構。並且由變溫核磁共振光譜所得之資訊,利用動力學研究來了解其機構且求得動力參數;以及找出軸向配位基—三氟醋酸根 (CF3COO–) 之重疊溫度 (Tc),進一步求得分子間化學交換的活化能 (ΔG) 來達到研究之目的。
URI: http://hdl.handle.net/11455/16489
其他識別: U0005-2107200616555600
Appears in Collections:化學系所

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