Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/16532
標題: 利用核磁共振光譜儀及X-光單晶繞射儀探討金屬大環錯化合物,M(Por)(L)n之分子結構,其中M =鎳、鉈,Por = (N-NCO-2-C4H3O-tpp)
Synthesis, Characterization and Molecular Structure Studies by NMR Spectroscopy and X-Ray Single-Crystal Determination On Metalloporphyrins : M(Por)(L)n, M = Ni and Tl , Por = (N-NCO-2-C4H3O-tpp)
作者: 施偉志
Shil, Wei-Zhil
關鍵字: X-ray;單晶繞射;NMR;thallium;porphyrin;核磁共振;鉈
出版社: 化學系所
引用: Reference: 1. Brothers, P. J. and Collman, J. P. Acc. Chem. Res. 1986, 19, 209-215. 2. McEwen,W. K. J. Am. Chem. Soc. 1946, 68, 711. Elling, R. C. and Corwin, A. H. J. Am. Chem. Soc. 1946, 68, 1112. Broadhurst, M. J.; Shelton, G. J. Chem. commun. 1970, 231. 3. Grigg, R.; Shelton, G.; Sweeney, A.; Johnson, A. W. J. Chem. Soc., Perkin Trans. 1 1972, 1789. 4. Wang, M. C.; Sue, L. S.; Liau, B. C.; Ko, B. T.; Elango, S.; Chen, J. H. Inorg. Chem. 2001, 40, 6064-6068. 5. Yang, C. H.; Tung, J. Y.; Liau, B. C.; Ko, B. T.; Elango, S. Hwang, L. P.;Chen, J. H. Polyhedron, 2001, 20, 3257–3264. 6. Tung, J. Y.; Liao, F. L.; Wang, S. L.; Chen, J. H. Inorg. Chem. 2000, 39, 2120-2124. 7. Karl M. Kadish, Kevin M. Smith,; Roger Guilard, The porphyrin Handbook Volume 1, Academic Press, 2000, pp 155-157. 8. Bonnett, R.; Ridge, R. J.; Appelman, E. H. J. Chem. Soc. Chem. Comm. 1978, 310-311. 9. Balch, A. L.; Chan, Y. W.; Olmstead, M. M.; Renner, M. W. J. Am. Chem. Soc. 1985, 107, 2393-2398. Arasasingham, R. D.; Balch, A. L.; Olmstead, M. M.; Renner, M. W. Inorg. Chem. 1987, 26, 3562-3568. 10. Balch, A. L.; Chan, Y. W. Inorg. Chem. Acta. 1986, 115, L45-L46. 11. Ichimura, K. Chem. Lett. 1976, 641-642. 12. Callot, H. J.; Chevrier, B.; Weiss, R. J. J. Am. Chem. Soc. 1978, 100, 4733.Callot, H. J. Tetrahedron, 1979, 35, 1455-1456. 13. Tung, J. Y.; Jang, J. I.; Lin, C. C.; Chen, J. H.; Hwang, L. P. Inorg. Chem. 2000, 39(6), 1106. 14. Han, I. I.; Kim, C.K.; Jung, H. J.; Lee, I. Theor. Chim. Acta. 1996, 93, 199. 15. Anet, Frank A. L.; Basus, V. J. J. of Magnetic Resonance.1978, 32, 339 16. Lunazzi, L.; Mazzanti, A. Spagnolo, P. J. Org. Chem. 1997, 62, 2263. 17. Kwon, Y. J. Mole. Stru.2000, 496, 217. 18.彭正吉, 碩士論文, 中興大學化學系, 民國九十四年.
摘要: 
我們合成出N-2-furoylcarboximido-meso-tetraphenyl porphyrin,並成功地合成出其鎳與鉈的錯化合物,且藉由1H-1H COSY,HSQC,HMBC及DEPT等核磁共振光譜來分析,並用X-RAY 單晶繞射鑑定其結構。探討其晶體結構、NMR光譜與動力學探討,環電流的效應與鉈與其醋酸根配位基的分子間交換。
URI: http://hdl.handle.net/11455/16532
其他識別: U0005-2806200621201700
Appears in Collections:化學系所

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