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標題: 吡唑苯酚基鋅及鎂錯合物之合成、鑑定及其對環酯類開環聚合反應之應用
Zinc and Magnesium Complexes Containing Pyrazolyl-phenolate Ligands: Synthesis, Characterization and Application in Ring-Opening Polymerization of Cyclic Esters
作者: 洪家祺
Hung, Chia-Chi
關鍵字: Zinc;鎂;Magnesium;Pyrazolyl-phenolate ligands;Ring-opening polymerization;吡唑苯酚配位基;開環聚合反應
出版社: 化學系所
引用: 1. (a) Y. Ikada and H. Tsuji, Macromol. Rapid Commun., 2000, 21, 117. (b) S. Mecking, Angew. Chem. Int. Ed., 2004, 43, 1078. 2. 3. N. E. Kamber, W. Jeong, R. M. Waymouth, R. C. Pratt, B. G. G. Lohmeijer and J. L. Hedrick, Chem. Rev., 2007, 107, 5813. 4. (a) A. Kumar and R. A. Gross, Biomacromolecules, 2000, 1, 133. (b) F. C. Loeker, C. J. Duxbury, R. Kumar, W. Gao, R. A. Gross and S. M. Howdle, Macromolecules, 2004, 37, 2450. (c) S. Matsumura, K. Mabuchi, and K. Toshima, Macromol. Rapid Commun., 1997, 18, 477. 5. (a) B. J. O’Keefe, M. A. Hillmyer and W. B. Tolman, J. Chem. Soc. Dalton Trans., 2001, 2215. (b) G. W. Coates, J. Chem. Soc., Dalton Trans., 2002, 467. (c) K. Nakano, N. Kosaka, T. Hiyama and K. Nozaki, Dalton Trans., 2003, 4039. (d) O. D. Cabaret, B. M. Vaca and D. Bourissou, Chem. Rev., 2004, 104, 6147. (e) J. Wu, T.-L. Yu, C.-T. Chen and C.-C. Lin, Coord. Chem. Rev., 2006, 250, 602. (f) R. H. Platel, L. M. Hodgson and C. K. Williams, Polym. Rev., 2008, 48, 11. (g) C. A. Wheaton, P. G. Hayes and B. J. Ireland, Dalton Trans., 2009, 4832. 6. (a) M. H. Chisholm, J. C. Gallucci and C. Krempner, Polyhedron, 2007, 26, 4436. (b) H. R. Kricheldorf, I. K. Saunders and C. Boettcher, Polymer, 1995, 36, 1253. (c) A. Kowalski, A. Duda and S. Penczek, Macromolecules, 1998, 31, 2114. 7. B.-T. Ko and C.-C. Lin, Macromolecules, 1999, 32, 8296. 8. (a) C. K. Williams, N. R. Brooks, M. A. Hillmyer and W. B. Tolman, Chem. Commun., 2002, 2132. (b) C. K. Williams, L. E. Breyfogle, S. K. Choi, W. Nam, V. G. Young, Jr., M. A. Hillmyer and W. B. Tolman, J. Am. Chem. Soc., 2003, 125, 11350. 9. A. Amgoune, C. M. Thomas and J.-F. Carpentier, Macromol. Rapid Commun., 2007, 28, 693. 10. (a) M. H. Chisholm, N. W. Eilerts, J. C. Huffman, S. S. Iyer, M. Pacold and K. Phomphrai, J. Am. Chem. Soc., 2000, 122, 11845. (b) B. M. Chamberlain, M. Cheng, D. R. Moore, T. M. Ovitt, E. B. Lobkovsky and G. W. Coates, J. Am. Chem. Soc., 2001, 123, 3229. 11. (a) B. Lian, C. M. Thomas, O. L. Casagrande, C. W. Lehmann, T. Roisnel and J.-F. Carpentier, Inorg. Chem., 2007, 46, 328. (b) B. Lian, C. M. Thomas, O. L. Casagrande Jr., T. Roisnel and J.-F. Carpentier, Polyhedron, 2007, 26, 3817. 12. Z. Zheng, G. Zhao, R. Fablet, M. Bouyahyi, C. M. Thomas, T. Roisnel, O. Casagrande Jr and J.-F. Carpentier, New J. Chem., 2008, 32, 2279. 13. C. Zhang and Z.-X. Wang, J. Organomet. Chem., 2008, 693, 3151. 14. (a) A. Otero, J. F. Baeza, A. Antiñolo, J. Tejeda and A. L. Sánchez, Dalton Trans., 2004, 1499. (b) C. Pettinari and R. Pettinari, Coord. Chem. Rev., 2005, 249, 663. 15. S. Milione, F. Grisi, R. Centore and A. Tuzi, Organometallics, 2006, 25, 266. 16. A. D. Schofield, M. L. Barros, M. G. Cushion, A. D. Schwarz and P. Mountford, Dalton Trans., 2009, 85. 17. (a) L. F. Sánchez-Barba, A. Garcés, M. Fajardo, C. Alonso-Moreno, J. Fernández-Baeza, A. Otero, A. Antiñolo, J. Tejeda, A. Lara-Sánchez and M. I. López-Solera, Organometallics, 2007, 26, 6403. (b) C. Alonso-Moreno, A. Garcés, L. F. Sánchez-Barba, M. Fajardo, J. Fernández-Baeza, A. Otero, A. Lara-Sánchez, A. Antiñolo, L. Broomfield, M. I. López-Solera and A. M. Rodríguez, Organometallics, 2008, 27, 1310. 18. A. Otero, J. Fernández-Baeza, A. Antiñolo, A. Lara-Sánchez, E. Martínez-Caballero, J. Tejeda, L. F. Sánchez-Barba, C. Alonso-Moreno and I. López-Solera, Organometallics, 2008, 27, 976. 19. (a) I. Cepanec, H. Mikuldaš and V. Vinković, Synth. Comm., 2001, 31, 2913. (b) M. Lanznaster, H. P. Hratchian, M. J. Heeg, L. M. Hryhorczuk, B. R. McGarvey, H. B. Schlegel and C. N. Verani, Inorg. Chem., 2006, 45, 955. (c) J.-Z. Wu, E. Bouwman, A. M. Mills, A. L. Spek and J. Reedijk, Inorg. Chim. Acta., 2004, 357, 2694. 20. (a) J. D. Farwell, P. B. Hitchcock, M. F. Lappert, G. A. Luinstra, A. V. Protchenko and X.–H. Wei, J. Organomet. Chem., 2008, 693, 1861. (b) H.-Y. Chen and C.-C. Lin, Acta Cryst., 2006, E62, m1693. (c) C.-T. Chen, W.-K. Chang, S.-C. Sheu, G.-H. Lee, T.-I. Ho, Y.-C. Lin and Y. Wang., J. Chem. Soc. Dalton Trans., 1991, 1569. 21. J. Ejfler, M. Kobyłka, L. B. Jerzykiewicz and P. Sobota, Dalton Trans., 2005, 2047. 22. (a) L. E. Breyfogle, C. K. Williams, V. G. Young, Jr., M. A. Hillmyer and W. B. Tolman, Dalton Trans., 2006, 928. (b) W.-C. Hung and C.-C. Lin, Inorg. Chem., 2009, 48, 728. (c) W.-C. Hung, Y. Huang and C.-C. Lin, J. Polym. Sci., Part A: Polym. Chem., 2008, 46, 6466. (d) Y. Huang, W.-C. Hung, M.-Y. Liao, T.-E. Tsai, Y.-L. Peng and C.-C. Lin, J. Polym. Sci., Part A: Polym. Chem., 2009, 47, 2318. 23. G. Deshayes, F. A. G. Mercier, P. Degée, I. Verbruggen, M. Biesemans, R. Willem and P. Dubois. Chem. Eur. J., 2003, 9, 4346. 24. (a) W. Yao, Y. Mu, A. Gao, W. Gao and L. Ye, Dalton Trans., 2008, 3199. (b) C. M. Silvernail, L. J. Yao, L. M. R. Hill, M. A. Hillmyer and W. B. Tolman, Inorg. Chem., 2007, 46, 6565. (c) P. Hormnirun, E. L. Marshall, V. C. Gibson, A. J. P. White and D. J. Williams, J. Am. Chem. Soc., 2004, 126, 2688. (d) H. Du, A. H. Velders, P. J. Dijkstra, Z. Zhong, X. Chen and J. Feijen, Macromolecules, 2009, 42, 1058. (e) W. Yao, Y. Mu, A. Gao, Q. Su, Y. Liu and Y. Zhang, Polymer, 2008, 49, 2486. 25. (a) 2007,何佳霖碩士論文,國立中興大學化學研究所。 (b) 2008,郭峻全碩士論文,國立中興大學化學研究所。 26. (a) M. Save, M. Schappacher and A. Soum, Macromol. Chem. Phys., 2002, 203, 889 (b) I. Palard, A. Soum and S. M. Guillaume, Macromolecules, 2005, 38, 6888. 27. (a) I. Barakat, P. Dubois, R. Jérôme and P. Teyssié, J. Polym. Sci., A: Polym. Chem., 1993, 31, 505 (b) H. Ma and J. Okuda, Macromolecules, 2005, 38, 2665. 28. H.-Y. Chen, H.-Y. Tang and C.-C. Lin, Macromolecules, 2006, 39, 3745.

A series of zinc and magnesium complexes containing pyrazolyl- phenolate ligands have been synthesized. Complexes 44-49 were characterized by NMR spectroscopy and elemental analysis. The molecular structures of complexes 44, 47 and 48 were determined by single-crystal X-ray diffraction techniques. Complexes 44-47 show efficient activity in the ring-opening polymerization of L-lactide and ε-caprolactone in the presence of benzyl alcohol, yielding polymers with controlled molecular weight and narrow molecular weight distribution. They also exhibit both “living” and “immortal” characters.
其他識別: U0005-0907200916580100
Appears in Collections:化學系所

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