Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/28300
標題: 以黏粒修飾電極法對甲基藍電化學特性之研究
Electroanalysis of Methylene Blue Using Clay-modified Electrode Method
作者: 何任于
Ho, Ren-Yu
關鍵字: clay minerals;黏土礦物;methylene blue;electroanalysis;甲基藍;電化學分析
出版社: 土壤環境科學系所
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摘要: 
甲基藍常廣泛被用於分析化學中氧化還原指示劑和光敏劑,其也可作為在環境中移動和傳輸的指標物。本試驗研究利用電化學分析的技術結合黏粒修飾電極來探討甲基藍在不同黏粒膜層中移動的情況和電化學行為。試驗結果指出掃描速率由慢到快及快到慢甲基藍在黏粒修飾電極上所測得之伏安圖的變化情形受到黏土礦物的種類與層面電荷所影響,且結果也發現甲基藍的電化學行為會受到掃描速率不同而改變。偵測甲基藍的同時加入對苯二酚觀察其電化學的變化,得知甲基藍與對苯二酚共同存在時會讓氧化還原電位往正電位方向偏移,電流量也相對增加。偵測甲基藍的同時加入放線菌觀察其電化學的變化,結果指出放線菌的的加入會使甲基藍的氧化還原電位往正電位方向偏移,膨潤石類修飾電極所偵測到的電流比未加入放線菌時來的低;而非膨潤石類修飾電極所偵測到的電流比未加入放線菌時來的高。試驗結果顯示若有對苯二酚和放線菌存在均會影響黏粒修飾電極表面上甲基藍的電化學反應行為,且隨著不同黏粒礦物種類有不同的影響,其中以膨潤石類的影響較為明顯。

Methylene blue was wildly used as a redox indicaor and photosensitizer in analytical chemistry, and that could be a model compound of mobilization and transportation in the environment. We studied electrochemical behavior of methylene blue using the technology of of eletroanalysis coupled with clay-modified electrode, and changed scan rate to study the migration of methylene blue in clay films. The results indicated the redox amounts of methylene blue were apparently affected by scan rate, and the cyclic coltammgrams were also affected by different layer charge of clay minerals. Redox potential shifted to more positive potential when methylene blue coexisted with hydroquinone in the electrolyte, and redox potential also shifted to more positive potential when actinomyces was added to methylene blue solution. Lower peak currents were detected in the methylene blue solution using smectite-modified electrode and higher peak currents were detected using other modified electrodes. The results showed hydroquinone and actinomyces could affect telectrochemical behavior of methylene blue in the clay films and the peak currents of methylene blue were apparently affected by smectite-modified electrodes.
URI: http://hdl.handle.net/11455/28300
其他識別: U0005-0908201116011200
Appears in Collections:土壤環境科學系

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