Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3200
標題: 含3,6-二噻吩吡咯併吡咯二酮衍生物之星狀分子合成及其光伏特性研究
Synthesis and Photovoltaic Properties of 3,6-Di(thiophen-2-yl) Diketopyrrolopyrrole Based Star Shaped Conjugate Molecules
作者: 張鈞賀
Chang, Chun-Ho
關鍵字: 含3,6-二噻吩吡咯併吡咯二酮;3,6-di(thiophen-2-yl)diketopyrrolopyrrole;三苯胺;異質接面有機太陽能電池;performance;bulk heterojunction cell
出版社: 化學工程學系所
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摘要: 
本篇論文設計,以拉電子基團三嗪 (trazine) 為中心體與含3,6-二噻吩吡咯併吡咯二酮形成共軛結構,在末端接上推電子基團 (donor) 三苯胺 (Triphenylamine, TPA),合成出星狀分子TDTTPA。經由NMR鑑定確認化學結構、經TGA與DSC分析熱性質熱裂解溫度為393 ℃、玻璃轉移溫度為120 ℃、結晶溫度為162 ℃、熔點溫度208 ℃,皆有不錯的熱穩定性。經紫外光-可見光分析光學TDTTPA成膜後,其最大吸收波長在333 nm 與640 nm ,經循環伏安法分析TDTTPA之HOMO分別為-5.35 eV而LUMO分別為-3.77 eV 。TDTTPA依不同比例與碳球衍生物PC61BM混合製成薄膜,以AFM觀察表面薄膜形態,發現TDTTPA與PC61BM 1:1.5(w/w) 比例混合製作成薄膜,具有最適合的微相分離,有助於電子電洞的傳遞。以TDTTPA/PC71BM複合膜作為光電轉換層,在80℃ 下熱處理1小時,製作成一系列光伏元件。其中以TDTTPA摻混PC71BM比例1:1.5(w/w) 表現最佳,電流密度Jsc值爲5.50 mA/cm2 、開路電壓VOC值爲0.72 V 、填充因子FF值爲0.31、光電轉換效率PCE值爲1.23 %。

The diketopyrrolopyrrole-based star-shaped molecules TDTTPA were synthesized and used as a donor for bulk heterojunction photovoltaic devices. The TDTTPA show two absorption band in the range of 300-700 nm with the maximum absorption wavelengths at around 333 and 640 nm, A series of bulk heterojunction solar cells based on the blend of TDTTPA and [6,6]-phenyl C71-butyric acid methyl ester (PC71BM) in different weight ratio were fabricated. The power conversion efficiency (PCE) was strongly dependent on the composition of the blends. The current density and PCE of the TDTTPA/PC71BM blend (1:1.5, w/w) based solar cell were 5.50 mAcm-2 and 1.23 %,respectivity.
URI: http://hdl.handle.net/11455/3200
其他識別: U0005-2607201316045400
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