Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3241
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dc.contributor林慶炫zh_TW
dc.contributor.author戴嵻宏zh_TW
dc.contributor.authorDai, Kang-Hongen_US
dc.contributor.other化學工程學系所zh_TW
dc.date2013en_US
dc.date.accessioned2014-06-06T05:31:32Z-
dc.date.available2014-06-06T05:31:32Z-
dc.identifierU0005-0108201311350900en_US
dc.identifier.citation1. 謝正悅,林慶炫,王春山,科學發展月刊,第28卷第11期,八 十九年九月。 2. Wang, T. S.;Yeh, J. F.;Shau, M. D. J. Appl. Polym.Sci. ,1996,59,215. 3. Liu,Y.L.;Hsiue,G.H;Lee,R.H.;Chiu,Y.S.J Appl Polym Sci 1997, 63, 895 4. Lin, C.H.;Wang, C.S. Polymer. 2001, 42,1869. 5. Cai, S.X.;Lin, C.H. J. Polym. Sci.:Part A: Polym. Chem. 2005, 43, 2862. 6. Holly, F. W.; Cope, C. J. Amer. Chem. Soc., 1944, 66, 1875. 7. Burke, W. J. J. Amer. Chem. Soc., 1949, 71, 609. 8. Ning, X.;Ishida, H. J. Polym. Sci., Part A: Polym. Chem. 1994,32,1121. 9. Brunovska, Z.;Ishida, H.;Liu, J.P. Macromol. Chem. Phys. 1999, 200,1745. 10. Lin, C.H. ; Chang, S.L. , Shen, T.Y.; Shih, Y.S.; Lin, H.T.; Wang, C.F. Polym. Chem., 2012, 3, 935. 11. Lin, C.H.;Lin,H.T.;Chang,S.H.;Hwang,H.J.;Hu,Y.M, ,Chiung Taso,Y.R. , Su,W,H, Polym.,2009, 50,2264. 12. 田諭瑋,” 含芴官能基的Benzoxazine與多官能磷系環氧樹脂硬化劑之合成”,中興大學碩士論文,民國100. 13. Shieh, J.Y.; Yang, S.P.; Wu, M.F.; Wang, C.S. J. Polym. Sci., Part A: Polym. Chem. 2004, 42, 2589. 14. Liu,C;Shen,D. ; Sebastian, R.M. ; Marquet, J. ; Schonfeld R. Macromol. , 2011, 44, 4616. 15. Wang X.;Chen F.;Gu Y. Polym. Sci., Part A: Polym. Chem. , 2011,49, 1443. 16. Liu Y. L. Polym. ,2001,42,3445. 17. DCI corporation,US2013/0040147,2013 18. Marvel, C.S; Tarkoy, N. J. Amer. Chem. Soc. 1957, 59, 6000. 19. Lin, C.H. ; Feng Y.R., Dai K.H., Chang H. C., Juang T. Y.Polym. Sci., Part A: Polym. Chem.2013 ,51, 2686 20. 彭筱萍,”新型多官能環氧樹脂硬化劑之合成及其固化物之特性,中興大學碩士論文,民國99.en_US
dc.identifier.urihttp://hdl.handle.net/11455/3241-
dc.description.abstractPART I 我們以P-BPN-3、P-BPN-5加入paraformaldehyde以及aniline利用Toluene/Ethanol(2:1)為溶劑,以一步法合成出P-BPN-3-BZ、P-BPN-5-BZ具有含磷多官能benzoxazine化合物,因為苯環上鄰位受亞甲基(-CH2-)阻擋,由FTIR追蹤推測出不同的開環聚合型式。利用DMA、TGA來探討3-BZ、5-BZ自身固化系統,以及各硬化劑與環氧樹脂 (DGEBA、CNE)固化系統機械性質與熱性質分析,並探討固化物介電性質及耐燃性質。 PART II 我們成功以D2HB、DOPO利用Toluene為溶劑合成出P-D2HB新穎雙官能酚基化合物,而且為一個diastereomers。以P-D2HB與DGEBA在TPP的催化下,合成改質出磷含量1.0%、1.5%、2.0%的化合物PD-D(1.0、1.5、2.0),以環氧滴定鑑定,並與DDS硬化劑,以當量比1:1固化,所得固化物與DGEBA/DDS固化物進行機械性質與熱性質比較,PD-D(1.0、1.5、2.0)/DDS玻璃轉移溫度還可以維持160℃以上,熱膨脹係數(CTE)維持在58~70 ppm/oC,由UL-94難燃測試,PD-D(1.0、1.5、2.0)/DDS都有優異的難燃特性。zh_TW
dc.description.abstractPART I We have successfully synthesized phosphorus-containing multifunctional benzoxazine, P-BPA-3b-BZ and P-BPA-5b-BZ by one-pot approach using toluene/ethanol (2/1) as solvent. Ring-opening polymerization types of curing systems were tracked by FTIR. The mechanical property, thermal stability, electrical property and flame retardancy of thermoset systems cured by various BZs with epoxy resins (DGEBA or CNE) were analyzed DMA, TGA, impedance analyzer and UL 94 flame rating. PART II A novel difunctional phenolic diastereomer, P-D2HB, from D2HB and DOPO, was successfully synthesized by using toluene as solvent. Catalyzed by TPP, various PD-D(1.0、1.5、2.0) with different phosphorus contents(1.0%、1.5%、2.0% )were synthesized from P-D2HB and DGEBA, and were characterized by epoxy titration method. All thermoset systems cured from PD-D with DDS demonstrated excellent properties in Tg(160℃up), CTE(58~70 ppm/oC) and flame retardancy.  en_US
dc.description.tableofcontents總目錄 摘要 i 第一章 緒論 1 第二章 文獻回顧 4 2.1含磷環氧樹脂硬化劑文獻回顧 4 2.2Benzoxazine簡介與文獻回顧 7 研究動機 13 PART I 13 第三章 實驗 14 3.1實驗藥品與溶劑 14 3.2 儀器設備 16 3.3 UL-94試驗 22 3.4實驗 23 PART I 23 3.4.1P-BPN-3-BZ(3-BZ)、P-BPN-5-BZ(5-BZ)合成 23 第四章 結果與討論 25 4.1光譜鑑定與分析 28 4.1.1 P-BPN-3-BZ光譜鑑定與分析 28 4.1.2 P-BPN-5-BZ光譜鑑定與分析 31 4.2. 傅立葉紅外線光譜分析 34 4.2.1P-BPN-3-BZ傅立葉紅外線光譜分析 34 4.2.2 P-BPN-5-BZ傅立葉紅外線光譜分析 35 4.3 P-BPN-3-BZ、P-BPN-5-BZ單體之DSC鑑定 36 4.4 Benzoxazine在不同溶劑下之合成與分析 38 4.5 Polybenzoxazine的合成與機制探討 44 4.6 P-BPN-3-BZ、P-BPN-5-BZ/CNE之DSC分析 48 4.7 P-BPN-3-BZ、P-BPN-5-BZ/CNE之傅立葉紅外線光譜分析 49 4.8試片硬化條件 51 4.9固化物之熱性質分析 55 4.10共聚物電氣性質鑑定分析 66 4.11固化物之難燃測試 68 第五章 結論 69 研究動機 71 PART II 71 3.1環氧當量(EEW)測定 73 3.2實驗 75 3.2.1 P-D2HB 合成 75 3.2.2 PD-D(1.0、1.5、2.0) 合成 76 第四章 結果與討論 77 4.1 P-D2HB光譜鑑定與分析 77 4.2. P-D2HB傅立葉紅外線光譜分析 82 4.3 P-D2HB單體之DSC鑑定 83 4.4 PD-D(1.0、1.5、2.0)環氧當量(EEW)滴定 84 4.5試片硬化條件 87 4.6固化物之熱性質分析 88 4.7固化物之難燃測試 93 第五章 結論 95 參考文獻 96zh_TW
dc.language.isozh_TWen_US
dc.publisher化學工程學系所zh_TW
dc.relation.urihttp://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-0108201311350900en_US
dc.subject磷系多官能zh_TW
dc.subjectphosphorus-containing multifunctionalen_US
dc.subject環氧樹脂zh_TW
dc.subjectbenzoxazinen_US
dc.subjecteepoxyen_US
dc.title磷系多官能benzoxazine型之合成及其固化物之探討zh_TW
dc.titlesynthesis of phosphorus-containing multifunctional benzoxazine and thermal properties of the resulting thermosetsen_US
dc.typeThesis and Dissertationzh_TW
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeThesis and Dissertation-
item.cerifentitytypePublications-
item.fulltextno fulltext-
item.languageiso639-1zh_TW-
item.grantfulltextnone-
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