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標題: Iron-Catalyzed Oxidative Cleavage of Olefins and Alkynes to Carboxylic Acids with Aqueous tert-Butyl Hydroperoxide
作者: Shaikh, Tanveer Mahamadali
Hong, Fung-E
關鍵字: tert-buyl hydroperoxide;carboxylic acids;iron;olefins;oxidation;TBHP;potassium-permanganate oxidations;hydrogen-peroxide;allylic oxidation;asymmetric epoxidation;copper(ii) complexes;mechanistic insights;selective oxidation;osmium tetraoxide;styrene oxida
Project: Advanced Synthesis & Catalysis, Volume 353, Issue 9, Page(s) 1491-1496.
A new method for the oxidation of aromatic olefins and alkynes has been developed using inexpensive iron(III) chloride hexahydrate (FeCl(3)center dot 6H(2)O, 5 mol%) catalyst in combination with commercially available aqueous 70% tert-butyl hydroperoxide (TBHP) as oxidant. The present system works well for aromatic alkenes and alkynes with both electron-donating and electron-withdrawing substituents being tolerated. The protocol is free from chromatographic purification and the carboxylic acids are obtained in high yields by simple filtration.
ISSN: 1615-4150
DOI: 10.1002/adsc.201000899
Appears in Collections:化學系所

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