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|標題:||Alkyne-mediated domino hydroformylation/double cyclization: mechanistic insight and synthesis of (+/-)-tashiromine||作者:||Chiou, Wen-Hua
|關鍵字:||stereoselective hydroformylation;indolizidine alkaloids;aza-annulation;(+)-tashiromine;tashiromine;route;(+/-)-5-epitashiromine;strategies;reduction;chemistry||Project:||Chemical Communications, Volume 47, Issue 12, Page(s) 3562-3564.||摘要:||
A novel domino reaction, alkyne-mediated domino hydroformylation/double cyclization, has been developed for rapid preparation of indolizidine type alkaloids. DFT calculations were applied for rationales of reactivity and selectivity. A concise synthesis of tashiromine as the application of the methodology is also reported.
|Appears in Collections:||化學系所|
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