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http://hdl.handle.net/11455/34073| 標題: | Application of MerCO as a chiral catalyst in asymmetric synthesis: asymmetric borane reduction of ketones | 作者: | Yang, T.K. 李東昇 Lee, D.S. |
關鍵字: | enantioselective reduction;aromatic ketones | Project: | Tetrahedron-Asymmetry | 期刊/報告no：: | Tetrahedron-Asymmetry, Volume 10, Issue 3, Page(s) 405-409. | 摘要: | The borane reduction of aryl methyl ketones catalyzed by MerCO [( 1R,2S,3R)-3-mercaptocamphan-2-ol] produced I-aryl ethyl alcohols in 92% e.e. at 50 degrees C in toluene. Significant temperature and solvent effects were observed in this reaction. (C) 1999 Elsevier Science Ltd. All rights reserved. |
URI: | http://hdl.handle.net/11455/34073 | ISSN: | 0957-4166 | DOI: | 10.1016/s0957-4166(98)00504-7 |
| Appears in Collections: | 化學系所 |
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