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|標題:||Application of MerCO as a chiral catalyst in asymmetric synthesis: asymmetric borane reduction of ketones||作者:||Yang, T.K.
|關鍵字:||enantioselective reduction;aromatic ketones||Project:||Tetrahedron-Asymmetry||期刊/報告no：:||Tetrahedron-Asymmetry, Volume 10, Issue 3, Page(s) 405-409.||摘要:||
The borane reduction of aryl methyl ketones catalyzed by MerCO [( 1R,2S,3R)-3-mercaptocamphan-2-ol] produced I-aryl ethyl alcohols in 92% e.e. at 50 degrees C in toluene. Significant temperature and solvent effects were observed in this reaction. (C) 1999 Elsevier Science Ltd. All rights reserved.
|Appears in Collections:||化學系所|
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