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標題: Bulky Bisphenol Ligand-Supported Aluminum-Sodium Inverse Crown Ether Complex
作者: Wu, J.C.
Pan, X.B.
Tang, N.
Lin, C.C.
關鍵字: macrocyclic amide;magnesium;chemistry;reagents
Project: Inorganic Chemistry
期刊/報告no:: Inorganic Chemistry, Volume 49, Issue 12, Page(s) 5362-5364.
A mixed aluminum sodium phenolate ring compound with an oxo core has been synthesized and crystallographically characterized as a new inverse crown ether complex, together with some of its. precursors. The experimental results showed that the Al-Na inverse crown ether can be obtained from two different approaches: (1) hydrolysis of KEDBP)Al(CH(3))(2)Na(THF)(2)] (1), followed by condensation with [(EDBP)Al(CH(3))(mu(2)-OH)Na(THF)(3)] (2); (2) fast redox reaction by oxidation of a methyl group on complex 1 and reduction of molecular oxygen to oxide.
ISSN: 0020-1669
DOI: 10.1021/ic1006555
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