Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34532
DC FieldValueLanguage
dc.contributor.authorHuang, Y.L.en_US
dc.contributor.author洪豐裕zh_TW
dc.contributor.authorWang, M.G.en_US
dc.contributor.authorHong, F.E.en_US
dc.date2006zh_TW
dc.date.accessioned2014-06-06T07:47:54Z-
dc.date.available2014-06-06T07:47:54Z-
dc.identifier.issn0009-4536zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/34532-
dc.description.abstractA cobalt-containing monodentate phosphine [(mu(2)-PPh2CH2PPh2-kappa P-2)Co-2(CO)(4)] [mu(2)-eta(2)-PhC equivalent to CP(i-Pr)(2)] 2f, was prepared from the reaction of (mu(2)-PPh2CH2PPh2-kappa P-2)Co-2(CO)(6) 1 with PhC equivalent to CP(i-Pr)(2). It was accompanied by an oxidized compound, [(mu(2)-PPh2CH2PPh2-kappa P-2)Co-2(CO)(4)][mu(2)-eta(2)-PhC equivalent to CP(=O)(i-Pr-2)] 2fo during the chromatographic process. Further reaction of 2f with MO(CO)(6) resulted in the formation of a 2f-ligated molybdenum complex 4, [(mu(2)-PPh2CH2PPh2-kappa P-2)Co-2(CO)(4)][mu(2)-eta(2)-PhC equivalent to CP(i-Pr-2)-kappa P]-Mo(CO)(5).en_US
dc.language.isoen_USzh_TW
dc.relationJournal of the Chinese Chemical Societyen_US
dc.relation.ispartofseriesJournal of the Chinese Chemical Society, Volume 53, Issue 5, Page(s) 1039-1044.en_US
dc.subjectmolybdenum complexen_US
dc.subjectmetal-containing phosphineen_US
dc.subjectcobalt complexen_US
dc.subjectDPPMen_US
dc.subjectsuzuki coupling reactionsen_US
dc.subjectpalladium-catalyzed aminationen_US
dc.subjectdicobalten_US
dc.subjectcarbonyl-complexesen_US
dc.subjectaryl chloridesen_US
dc.subjectarylboronic acidsen_US
dc.subjectconvenienten_US
dc.subjectbromidesen_US
dc.titlePreparation and characterization of a cobalt-containing mono-phosphine ligand and its coordinated molybdenum complexen_US
dc.typeJournal Articlezh_TW
item.languageiso639-1en_US-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.openairetypeJournal Article-
item.fulltextno fulltext-
item.grantfulltextnone-
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