Preparation and characterization of trimethylsilyipyridylacetylene bridged, dicobalt carbonyl complexes containing bis(diphenylphosphino)methylene or bis(diphenylphosphino)ethylene ligand

DSpace CRIS

Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34536

標題:	Preparation and characterization of trimethylsilyipyridylacetylene bridged, dicobalt carbonyl complexes containing bis(diphenylphosphino)methylene or bis(diphenylphosphino)ethylene ligand
作者:	Hong, F.E. 洪豐裕 Chang, Y.C. Chen, C.W. Huang, Y.L.
關鍵字:	alkyne-bridged dicobalt complex;bis(diphenylphosphino)methylene;bis(diphenylphosphino)ethylene;hydrogen bonding;organocobalt complexes
Project:	Journal of the Chinese Chemical Society
期刊/報告no：:	Journal of the Chinese Chemical Society, Volume 50, Issue 5, Page(s) 973-978.
摘要:	Reaction of an alkyne-bridged dicobalt complex, [CO2(CO)(6)(mu-Me(3)SiCdropCpy)] 4, with bis(diphenylphosphino)methylene (DPPM) or bis(diphenylphosphino)ethylene (DPPE) in THF at 55 degreesC yielded a DPPM or DPPE doubly bridged dicobalt compound, [{mu-P,P-PPh2CH2PPh2}Co-2(CO)(4)(mu-Me(3)SiCdropCpy)] 5 or [{mu-P,P-PPh2CH2CH2PPh2}Co-2(CO)(4)(mu-Me(3)SiCdropCpy)] 6. Compound 5 and 6 were characterized by spectroscopic means as well as X-ray crystal structure determination.
URI:	http://hdl.handle.net/11455/34536
ISSN:	0009-4536
Appears in Collections:	化學系所

Show full item record

TAIR Related Article

Check