Saddle-shaped six-coordinate iron(III) porphyrin complex with unusual intermediate-spin electronic structure

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Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34636

標題:	Saddle-shaped six-coordinate iron(III) porphyrin complex with unusual intermediate-spin electronic structure
作者:	Cheng, R.J. 陳如珍 Chao, C.W. Han, Y.P. Chen, Y.C. Ting, C.H.
關鍵字:	transition-state method;fock-slater method;c-13 nmr;approximation;configuration;deformation;crossover;ligands;energy;s=1/2
Project:	Chemical Communications
期刊/報告no：:	Chemical Communications, Issue 16, Page(s) 2180-2182.
摘要:	An unusual intermediate-spin electronic structure d(xz,yz)(3)d(xy)(1)d(z2)(1) has been assigned to the six-coordinate saddled [Fe(OETPP)(4-CNPy)(2)](+) complex through density functional calculation and NMR spectroscopy analysis.
URI:	http://hdl.handle.net/11455/34636
ISSN:	1359-7345
DOI:	10.1039/b820443h
Appears in Collections:	化學系所

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