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|標題:||Anomalous (CNMR)-C-13 chemical shifts of high-spin saddle shaped manganese(III) octaethyltetraphenylporphyrin complexes||作者:||Ikezaki, A.
|關鍵字:||iron(iii) porphyrin complexes;nmr-spectroscopy;c-13;metalloporphyrins;s=1/2||Project:||Chemistry Letters||期刊/報告no：:||Chemistry Letters, Volume 35, Issue 2, Page(s) 156-157.||摘要:||
NMR spectra of highly saddled Mn(III) porphyrinates such as Mn(OETPP)(CD3OD)(2)(+) have been measured. The extraordinarily upfield shifted meso-C-13 signals, which reach as much as -492 ppm at 298 K, are ascribed to the d(x2-y2)-a(2u), d(xy-a1u), and d(pi)-3e(g) interactions, the former two of which occur only when the porphyrin ring is saddled.
|Appears in Collections:||化學系所|
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