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|標題:||Microwave accelerated cycloaddition reactions of nitrile oxides and allylic alcohols||作者:||Lu, T.J.
|關鍵字:||microwave;nitrile oxide;cycloaddition;allylic alcohol;isoxazoline;regioselectivity;1,3-dipolar cycloaddition;chemical-reactions;isoxazoline route;organic-synthesis;chemistry;chlorides;additions;ketones;beta||Project:||Journal of the Chinese Chemical Society||期刊/報告no：:||Journal of the Chinese Chemical Society, Volume 47, Issue 1, Page(s) 189-196.||摘要:||
The application of microwaves in promoting the cycloaddition reactions of allyl alcohols with nitrile oxides using a domestic microwave oven and a focused monomode microwave reactor have demonstrated that not only was the reaction time substantially reduced, but also the reaction yields were significantly improved over the conventional stirred reactions. Microwave irradiation alters the regioselectivity of the cycloaddition reaction which favors the non-hydrogen-bond directed cycloadduct, isoxazoline 4.
|Appears in Collections:||化學系所|
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