Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34818
DC FieldValueLanguage
dc.contributor.authorKumar, A.S.en_US
dc.contributor.author曾志明zh_TW
dc.contributor.authorChen, P.Y.en_US
dc.contributor.authorZen, J.M.en_US
dc.date2004zh_TW
dc.date.accessioned2014-06-06T07:48:24Z-
dc.date.available2014-06-06T07:48:24Z-
dc.identifier.issn1040-0397zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/34818-
dc.description.abstractIndustrial waste cinder (CFe*) has been utilized as a stable anchoring matrix for self-assembling of Fe(CN)(6)(3-) as hybrid Prussian blue units (PB, *(Fe3+FeII)(CN)(6)) on a screen-printed carbon electrode (SPE) for efficient catalytic applications. The waste cinder was found to be a composite of calcium and iron silicates similar to glass matrix by Xray photoelectron spectroscopic (XPS) study. The hybrid PB formations were confirmed by both FT-IR and electrochemical methods. Most importantly, the free iron (Fe*) ion bound to the non-bridging oxygen terminals of the silicates was found to play a key role in the PB formation. The self-assembled PB hybrid on the cinder-modified screen-printed electrodes (designated as PBCFe*-SPE) improved linear detection range and sensitivity for H2O2 mediated oxidation than those obtained at a classical PB-SPE in 0.1 M, pH 2 KCl/HCl base electrolyte at 0.0 V (vs. Ag/AgCl) by amperometric batch analysis.en_US
dc.language.isoen_USzh_TW
dc.relationElectroanalysisen_US
dc.relation.ispartofseriesElectroanalysis, Volume 16, Issue 3, Page(s) 242-246.en_US
dc.relation.urihttp://dx.doi.org/10.1002/elan.200302774en_US
dc.subjectPrussian blueen_US
dc.subjectcinderen_US
dc.subjectcharacterizationen_US
dc.subjectelectrocatalysisen_US
dc.subjectflow-injection analysisen_US
dc.subjectsilicate glassen_US
dc.subjectsurface modificationen_US
dc.subjectpasteen_US
dc.subjectelectrodesen_US
dc.subjectoxidaseen_US
dc.subjectxpsen_US
dc.titleSelf-assembling of hybrid Prussian blue units in cinder matrix: Characterization and electrocatalysisen_US
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1002/elan.200302774zh_TW
item.languageiso639-1en_US-
item.openairetypeJournal Article-
item.cerifentitytypePublications-
item.grantfulltextnone-
item.fulltextno fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
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