Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/34871
標題: Improved flow injection analysis of H2O2 on cinder/Prussian Blue-modified electrodes by CTAB micelles
作者: Zen, J.M.
曾志明
Chen, P.Y.
Kumar, A.S.
關鍵字: cinder;Prussian Blue;screen-printed electrode;CTAB;hydrogen peroxide;prussian-blue;hydrogen-peroxide;surfactants;films;biosensors;reduction;analogs
Project: Journal of the Chinese Chemical Society
期刊/報告no:: Journal of the Chinese Chemical Society, Volume 49, Issue 5, Page(s) 915-920.
摘要: 
In the present work, a new strategy involving the addition of CTAB at its critical micelle concentration was developed to improve the electrochemical properties of the cinder/PB-modified screen-printed electrode (designated as cinder/PB-SPE) in the detection of H2O2 by flow injection analysis (FIA). Such new PB hybrids derived from cinder have remarkable stability even under strong hydrodynamic stress. The cylindrical CTAB micelles formed at the 2(nd) critical micelle concentration can effectively promote the PB redox behavior. Under optimized conditions with pH 7 PBS + 7 mM CTAB as carrier solution in FIA, a linear calibration was obtained up to 25 muM H2O2 with slope, regression coefficient, and detection limit (S/N = 3) of 1.03 A/Mcm(2), 0.995, and 4.02 muM respectively. Interferences by direct electrochemical oxidation of easily oxidizable substances can be prevented due to the low detecting potential of the working system.
URI: http://hdl.handle.net/11455/34871
ISSN: 0009-4536
Appears in Collections:化學系所

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