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標題: Ortho-alkylation of phenol with methanol using Pb-Cr promoted magnesium oxide catalysts
作者: Ke, J.H.
Zen, J.M.
Wang, F.L.
關鍵字: Pb-Cr promoted;ortho-alkylation;phenol;ka-oil;2,6-dimethylphenol;zeolite
Project: Journal of the Chinese Chemical Society
期刊/報告no:: Journal of the Chinese Chemical Society, Volume 51, Issue 6, Page(s) 1407-1410.
In this study, Pb-Cr promoted magnesium oxide catalysts were used to catalyze the ortho-alkylation of phenol in the presence of excess methanol. The Cr/MgO catalyst exhibited a high conversion of phenol and a relatively high selectivity for the ortho-alkylation of phenol. The catalytic activity and the stability of Cr/MgO were improved by the addition of a fairly small amount of Pb. The Pb-Cr/MgO catalyst showed specificity for the ortho-alkylation of phenol, which was proved by a series of phenol derivative reactions with methanol.
ISSN: 0009-4536
Appears in Collections:化學系所

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