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標題: Sensitive determination of zinc(II) in real samples using a poly(4-vinylpyridine)/mercury film electrode
作者: Zen, J.M.
Tsai, D.M.
Yang, H.H.
關鍵字: zinc;poly(4-vinylpyridine);mercury film electrode;anodic-stripping voltammetry;glassy-carbon electrodes;cellulose-acetate;copper;interferences;suppression;membranes
Project: Journal of the Chinese Chemical Society
期刊/報告no:: Journal of the Chinese Chemical Society, Volume 50, Issue 3A, Page(s) 375-380.
A poly(4-vinylpyridine)/mercury film electrode (PVP/MFE) was applied for the determination of trace amounts of zinc ion by square-wave anodic stripping voltammetry. The PVP/MFE shows better mechanical stability, higher sensitivity, and enhanced resistance to common ions and surface-active compounds than conventional mercury film electrodes. Various experimental parameters affecting the performance of the PVP/ MFE in Zn(II) determination were optimized. Under the optimized conditions, the PVP/MFE shows a linear response up to 50 mug l(-1) with a detection limit (S/N = 3) of 1.7 mug l(-1). The practical applicability of the electrode was evaluated through the analytical estimation of Zn(II) in various real samples.
ISSN: 0009-4536
Appears in Collections:化學系所

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