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http://hdl.handle.net/11455/34962| 標題: | New highly nucleophilic and practically accessible chlorocarbenoids for carbonyl olefination | 作者: | Tsai, C.C. 楊圖信 Chien, C.T. Chang, Y.C. Lin, H.C. Yan, T.H. |
關鍵字: | c-h insertion;alkylidene carbene;methylenation;ketones;activation;halides;dichloromethane;conversion;chemistry;synthon | Project: | Journal of Organic Chemistry | 期刊/報告no：: | Journal of Organic Chemistry, Volume 70, Issue 14, Page(s) 5745-5747. | 摘要: | Direct oxidative addition of CHCl3 to the Mg-TiCl4 bimetallic species resulted in the generation of a highly nucleophilic and practically convenient chloromethylenetitanium complex, which efficiently effected condensation even with enolizable or inert carbonyl compounds, such as sterically congested ketones, to provide vinyl chloride compounds. |
URI: | http://hdl.handle.net/11455/34962 | ISSN: | 0022-3263 | DOI: | 10.1021/jo050455c |
| Appears in Collections: | 化學系所 |
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