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標題: Purge-assisted headspace solid-phase microextraction combined with gas chromatography/mass spectrometry for the determination of trace nitrated polycyclic aromatic hydrocarbons in aqueous samples
作者: Hung, Cheng-Han
Ho, Hsin-Pin
Lin, Mei-Tzu
Chen, Chung-Yu
Shu, Youn-Yuen
Lee, Maw-Rong
關鍵字: Nitrated polycyclic aromatic hydrocarbons;Gas chromatography/mass spectrometry;Purge-assisted headspace solid phase;microextraction;Negative ion chemical ionization
Project: Journal of Chromatography A, Volume 1265, page(s) 1– 6.
This study describes a new procedure, namely, purge-assisted headspace solid phase microextraction
combined with gas chromatography/negative ion chemical ionization mass spectrometry (PA/HS-SPMEGC/
NICI-MS), which is used to determine seven nitrated polycyclic aromatic hydrocarbons (NPAHs) in
aqueous samples. High extraction efficiency was obtained with PA/HS-SPME with polydimethylsiloxane
(PDMS) fiber coating. A programmable temperature vaporizing (PTV) inlet was used in the desorption
process. Selected ion monitoring (SIM) was used for quantitative and qualitative purposes. The linear
range of detection of the proposed method was 5–5000 pg/mL with coefficients of determination
between 0.995 and 0.999. Limits of detection (LODs) for seven NPAHs were 0.01–0.06 pg/mL. The relative
standard deviation was below 12.7% at a concentration of 50 pg/mL. Compared with headspace-solid
phase microextraction (HS-SPME), the purge procedure enhanced the extraction efficiency for high boiling
point analytes, such as 7-nitrobenz[a]anthracene (7-NBA) and 6-nitrochrysene (6-NC). The proposed
method provides a sensitive method for NPAH analysis at the pg/mL level. The application of the proposed
method for the determination of trace NPAHs in real samples was investigated by analyzing aqueous samples
from rivers. The concentrations of NPAHs detected from the samples ranged from 5.2 to 7.5 pg/mL.
This method was applied successfully in the analysis of trace NPAHs in river samples.
ISSN: 0021-9673
DOI: 10.1016/j.chroma.2012.09.084
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