Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3689
標題: 高性能含磷高分子Benzoxazine及聚醯亞胺之合成與應用
Synthesis and Characterization of High Performance Phosphorus-containing Polybenzoxazines and Polyimides.
作者: 張家瑋
Chang, Chia-Wei
關鍵字: benzoxazine;聚醯亞胺;polyimide;phosphorus;flame retardancy;high Tg;磷;難燃;高玻璃轉移溫度;氧代氮代苯并環己烷
出版社: 化學工程學系所
引用: Reference of chapter 1. 1. Ning, X.; Ishida, H. J. Polym. Sci., Part A: Polym. Chem. 1994, 32, 1121. 2. Ishida, H.; Allen, D. J. J. Polym. Sci., Part B: Polym. Phys. 1996, 34, 1019. 3. Takeichi, T.; Komiya, I.; Takayama, Y. Kyoka-Purasutikkus 1997, 43, 109. 4. Ishida, H.; Low, H. Y. Macromolecules 1997, 30, 1099. 5. Wang, Y. X.; Ishida, H. Polymer 1999, 40, 4563. 6. Shen, S. B.; Ishida, H. J. Polym. Sci., Part B: Polym. Phys. 1999, 37, 3257. 7. Macko, J. A.; Ishida, H. Polymer 2001, 42, 227. 8. Wang, C. F.; Su, Y. C.; Kuo, S. W.; Huang, C. F.; Sheen, Y. C.; Chang, F. C. Angew. Chem., Int. Ed. 2006, 45, 2248. 9. Macko, J. A.; Ishida, H. Polymer 2001, 42, 227. 10. Takeichi, T.; Guo, Y.; Agag, T. J. Polym. Sci., Part A: Polym.Chem. 2000, 38, 4165. 11. Ishida, H.; Lee, Y. J. Polym. Sci., Part B: Polym. Phys. 2001, 39, 736. 12. Jang, J.; Yang, H. J. Mater. Sci. 2000, 35, 2297. 13. Takeichi, T.; Zeidam, R.; Agag, T. Polymer 2002, 43, 45. 14. Agag, T.; Takeichi, T. Macromolecules 2003, 36, 6010. 15. Brunovska, Z.; Ishida, H. J. Appl. Polym. Sci. 1999, 73, 2937. 16. Kim, H. J.; Brunovska, Z.; Ishida, H. Polymer 1999, 40, 1815. 17. Agag, T.; Takeichi, T. Macromolecules, 2001, 34, 7257. 18. Li, S.; Wang, L. J Appl polym sci 2006, 99,1359. 19. Lin, C. H.; Chang, S. L.; Hsieh, C. W.; Lee, H. H. Polymer 2008, 49, 1220. 20. Wang, C. S.; Berman, J. R.; Walker, L. L.; Mendoza, A. J Appl Polym Sci 1991, 43, 1315. 21. Wang, C. S.; Sun, Y. M.; Mendoza, A. Org Prepr Proc Int 1992, 24, 176. 22. Liu, Y. L. J Polym Sci Part A: Polym Chem 2002, 40, 359. 23. Liu, Y. L.; Tsai, S. H. Polymer 2002, 43, 5757. 24. Lin, C. H. Polymer 2004, 25, 7911. 25. Liu, Y. L.; Wu, C. S.; Hsu, K. Y.; Chang, T. C. J Polym Sci Part A: Polym Chem 2002, 40, 2329. 26. Ge, X. G.; Wang, C.; Hu, Z.; Xiang, X.; Wang, J. S.; Wang, D. Y.; Liu, C. P.; Wang, Y. Z. J Polym Sci Part A: Polym Chem 2008, 46, 2994. 27. Canadell, J.; Manteco'n, A.; Ca'diz, V. J Polym Sci Part A: Polym Chem 2007, 45, 1920. 28. Lligadas, G.; Ronda, J. C.; Galia`, M.; Ca'diz, V. J Polym Sci Part A: Polym Chem 2006, 44, 6717. 29. Yang, H.; Yang C. Q.; Ind. Eng. Chem. Res. 2008, 47, 2160. 30. Lin, C. H.; Feng, C. C.; Hwang, T. U. Euro Polym J 2007, 43, 725. 31. Cai, S. X.; Lin, C. H. J Polym Sci Part A: Polym Chem 2005, 43, 2862. 32. Brunovska, Z.; Liu, J. P.; Ishida, H. Macromol Chem Phys 1999, 200, 1745. 33. Lin, C. H.; Cai, S. X.; Leu, T. S.; Hwang, T. Y.; Lee, H. H. J Polym Sci Part A: Polym Chem 2006, 44, 3454. 34. Kim, H. J.; Brunovska, Z.; Ishida, H. Polymer 1999, 40, 1815. 35. Kim, H. J.; Brunovska, Z.; Ishida, H. Polymer 1999, 40, 6565. Reference of chapter 2. 1. Mittal KL, Ed., Polyimides: Synthesis, Characterization, Application, Plenum Press, New York, 1984, vols. 1 and 2. 2. Xu JW, He CB, Chung TS. J Polym Sci Part A: Polym Chem 2001, 39, 2998. 3. Hsiao SH, Chung CL, Lee ML. J Polym Sci Part A: Polym Chem 2004, 42, 1008. 4. Spilliopoulos IK, Mikroyannidis JA, Tsivgoulis GM. Macromolecules 1998, 31, 522. 5. Ayala D, Lozana AE, Abajo JD, Campa JGDL. J Polym Sci Part A: Polym Chem 1999, 37, 805. 6. Liaw DJ, Liaw BY, Lai SH. Macromol Chem Phys 2001, 202, 807. 7. Chung IS, Kim SY. Macromolecules 1998, 31, 5920. 8. Hsiao SH, Li CT. Macromolecules 1998, 31, 7213. 9. Liaw DJ, Liaw BY, Macromolecules 1999,32,7248. 10. Yi MH, Huang WMY, Choi KY. Macromolecules 1997, 30, 5606. 11. Watson KA, Palmieri FL, Connell JW. Macromolecules 2002, 35, 4968. 12. Kwak SM, Yeon JH, Yoon TH. J. Polym. Sci. Part A: Polym. Chem. 2006, 44, 2567. 13. Liu YL, Hsiue GH, Lan CW, Kuo JK, Jeng RJ, Chiu YS J Appl Polym Sci 1997, 63, 875. 14. Banerjee S, Palit SK, Maiti S. J. Polym. Sci. Part A: Polym. Chem. 1994, 32, 219. 15. Nair PR, Glouet G, Guilbert Y. Polym. Degrad. Stab. 1992, 26, 305. 16. Baillet C, Gandi S, Breant P, Delfosse L. Polym. Degrad. Stab. 1992, 37, 149. 17. Banks M, Ebdon JR, Johnson M. Polymer 1993, 34, 4547. 18. Banks M, Ebdon JR, Johnson M. Polymer 1994, 35, 3470. 19. Banerjee S, Palit SK, Maiti S. J. Polym. Sci. Polym. Chem. 1994, 32, 219. 20. Horrocks AR, Zhang J, Hall ME. Polymer. Int. 1994, 33, 303. 21. Kannan P, Kishore K. Eur. Polym. J. 1991, 27, 1017. 22. Meyer GW, Pak SJ, Lee YJ, McGrath JE. Polymer 1994, 36, 2303. 23. Myung BY, Ahn CJ, Yoon TH. J Appl Polym Sci 2005, 96, 1801. 24. Jeong KU, Kim JJ, Yoon TH. Polymer 2001, 42, 6019. 25. Liou GS, Hsiao SH. J. Polym. Sci. Part A: Polym. Chem. 2001, 39, 1786. 26. Maiti S, Banejee S, Palit SK. Prog Polym Sci 1993, 18, 227. 27. Liu YL, Hsu CY, Wu CS. J Appl Polym Sci 2003, 89, 791. 28. Lin CH, Lin CH. J Polym Sci Part A: Polym. Chem. 2007, 45, 2897. 29. Lin CH, Wang CS. Polymer 2001, 42, 4869. 30. Liu YL, Hsiu GH, Lee RH, Chiu YS. J Appl Polym Sci 1997, 63, 895. 31. G. K. Yokohama, I. H. Machida. DE patent. DE 3526010 A1, 1984.
摘要: 
The reported includes Part A and Part B. Part A is about an aromatic triamine- based flame-retardant benzoxazine (3), which can't be prepared by traditional one-step procedure, was successfully prepared by a three-step procedure. The structures of (3) and two intermediates (1-2), were confirmed by IR, high-resolution mass, 1H and 31P NMR spectra. (3) was copolymerized with commercial benzoxazines (F-a) and (P-d) to improve the thermal and flame retardant properties. The effects of (3) on the thermal properties, dynamic mechanical properties, thermal mechanical properties and flame retardancy of copolybenzoxazines were investigated.
Part B is about two novel phosphorus-functionalized aromatic diamines, 1,1-bis(4-aminodiphenyl)-1-(6-oxido-6H-dibenz <1,2> oxaphosphorin-6-yl) ethane (1) and bis(4-aminodiphenyl)-(6-oxido-6H-dibenz <1,2> oxaphosphorin -6-yl)-phenylmethane (2), were synthesized via a one-pot procedure. A SN1 mechanism was proposed for the preparation. A series of polyimides (5a-5d, 6a-6d) with bulky biphenylene phosphinate pendant were prepared from the condensation of (1-2) with various aromatic dianhydrides in DMAc, followed by thermal imidization. Polyimides (5a-5d) are flexible and creasable, and display high Tg (318-392 oC), high moduli (3.39-4.49 GPa), low coefficient of thermal expansion (42-50 ppm/ oC), and high thermal stability (5 wt% degradation temperatures at 426-439 oC). In contrast, polyimides (6a-6d) are brittle due to the rigid structure and two bulky substituents retard the mobility of the molecular chains.
URI: http://hdl.handle.net/11455/3689
其他識別: U0005-1707200812065700
Appears in Collections:化學工程學系所

Show full item record
 
TAIR Related Article

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.