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標題: 以綠色化學程序合成聚胺酯-脲素樹酯之中間體
Green Chemistry Synthesis of Intermediates for Polyurethane-urea
作者: 林照興
Lin, Chao-Hsing
關鍵字: 聚胺酯-脲素樹酯;polyurea;dimethyl 4, 4'-methylene diphenylcarbamate;diphenyl 4, 4'-methylene diphenylcarbamate;Amination;chemical recycling;ethoxylation;propoxylation;PC recycling
出版社: 化學工程學系所
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In this research, two green chemical processes for synthesizing intermediates for polyurethane-urea have been developed successfully. Firstly, environmental friendly processes of non-phosgene approach to two 4, 4'-methylene diphenylcarbamates and isocyanate-free routes based on these intermediates to urea-prepolymers and polyureas have been devised. Secondly, one-pot reaction process with digestion and alkoxylation of the polycarbonate wastes conversion into bishydroxyalky ethers of bisphenol A for use as polyurethane raw materials also have been developed.
In the part one of my study, I worked out a practical synthesis of amine-terminated urea prepolymers and polyureas through the amination of dimethyl 4, 4'-methylene diphenylcarbamate (4, 4'-DM-MDC) and diphenyl 4, 4'-methylene diphenylcarbamate (4, 4'-DP-MDC) in a novel non-phosgene route. The preparation of 4, 4'-DM-MDC was achieved by condensation of methyl N-phenylcarbamate with formaldehyde using concentrated hydrochloric acid as a promotor in a methanol solution at 30 oC. Under these conditions, the result has improved to a 91 % conversion based on methyl N-phenylcarbamate with the selectivity of 2, 4'-DM-MDC at 2 % and 4, 4'-DM-MDC at 91 %. On the other hand, we performed a carbonylation of 4, 4'-methylenedianiline (4, 4'-MDA) with diphenyl carbonate with pivalic acid at 80 oC as the catalyst to achieve the highest yield of 94 % for 4, 4'-DP-MDC.
Amination of 4, 4'-DM-MDC with high boiling-point polyetherdiamines resulted in rapid removal of methanol at around 160 oC to produce amine terminated urea-prepolymers which by reaction with a diisocyanate such as diphenylene diisocyanate (MDI), formed polyureas. This approach however, failed to give high molecular weight polyureas directly when equal moles of short-chained diamines and 4, 4'-DM-MDC were mixed in a one-pot reaction process. On the other hand, amination of 4, 4'-DP-MDC was found to be more efficient than those of 4, 4'-DM-MDC, and could be used for both polyureas and a hydroxyl terminated urea-prepolymer synthesis. The preparation of hydroxyl terminated urea-prepolymer, like 4, 4'-diphenylmethanebis-[(2-hydroxyethyl)urea] for instance, can be prepared in high yield of 97% in minutes, from amination of 4, 4'-DP-MDC and ethanol amine. More conveniently, a one-pot amination of 4, 4'-DP-MDC with a diamine or mixed diamines was also found to be an excellent method for the preparation of high molecular weight polyureas. Thus, the amination approach using 4, 4'-DP-MDC as the key intermediate provides a general and excellent green chemistry route for introducing methylene diphenylene units into urea-prepolymers and polyurea elastomers without using phosgene or diphenylmethane diisocyanate in the overall process
An efficient process of the chemical recycling of polycarbonate (PC) waste into diols of bis-phenol A (BPA) for use as raw materials in PU production also has been developed. This is another development of green process of making PU intermediates through waste materials. Digestion of PC waste in alkylene glycols, i.e., ethylene glycol (EG) and propylene glycol (PG), with catalytic amount of sodium carbonate at 180 oC under normal atmosphere pressure afforded partial alkoxylation products of BPA. This initial product mixture was found to be consisting of BPA (28 %) and monohydroxyethyl ether (MHE-BPA, 40 %) and bishydroxyethyl ether of bisphenol A (BHE-BPA, 25 %) when digested in EG solution. Whereas, in PG digestion solution, the corressponding digestion products consist of monohydroxyproply ether of BPA (MHP-BPA, 53 %) and bishydroxypropyl ether of BPA (BHP-BPA, 21 %) with the rest being un-propoxylated BPA (26%). When these digested solutions were further treated with molar excess of urea with a catalytic amount of zinc oxide at 180 oC, BHE from EG or BHP-BPA from PG was produced in high yields. In both digestion processes, cyclic alkylene carbonates, i. e. ethylene carbonate (EC) or propylene carbonate (PPC), were observed as the transient intermediates which eventually disappears during the prolonged alkoxylation conditions. ZnO was added to the second step as the catalyst to accelerate urea's trans-esterification process. Both BHE and BHP products have been successfully utilized in making PU polymers of good mechanical properties. This chemical approach thus provides a viable alternative for PC recycling.
其他識別: U0005-1808200811502900
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