Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3723
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dc.contributor鄭如忠zh_TW
dc.contributor羅介聰zh_TW
dc.contributor.advisor林慶炫zh_TW
dc.contributor.author方鈺婷zh_TW
dc.contributor.authorFang, Yu-Tingen_US
dc.contributor.other中興大學zh_TW
dc.date2010zh_TW
dc.date.accessioned2014-06-06T05:32:36Z-
dc.date.available2014-06-06T05:32:36Z-
dc.identifierU0005-0608200916233100zh_TW
dc.identifier.citation1. 呂奇明,韋光華,“低介電多面體倍半矽氧烷寡聚物(POSS)/聚亞醯胺奈米複合材料之合成與性質分析”,交通大學博士論文,民國91年. 2. Chen, B. K.; Fang, Y. T.; Cheng, J. R. Macromolecular Symposia 2006, 242, 34. 3. 蔡宇傑,蔡三元,“Kapton 聚醯亞胺樹脂之改質研究”,成功大學碩士論文,民國93年. 4. Hu, Z. Q.; Wang, M. H.; Li, S. J.; Liu, X. Y.; Wu, J. H. Polymer 2005, 46, 5278. 5. Spiliopoulos, I. K.; Mikroyannidis, J. A. Macromolecules 1998, 31, 1245. 6. Oishi, Y.; Ishida, M.; Kakimoto, M. A.; Imai, Y.; Kurosaki, T. J Polym Sci Part A: Polym Chem 1992, 30, 1027. 7. Biolley, N.; Gregoire, M.; Pascal, T.; Sillion, B. Polymer 1991, 32, 17. 8. Zhang, Q. Y.; Li, S. H.; Li, W. M.; Zhang, S. B. Polymer 2007, 48, 6246. 9. Yang, C. P.; Lin, J. H. J Polym Sci Part A: Polym Chem 1993, 31, 2153. 10. Hsiao, S. H.; Li, C. T. J Polym Sci Part A: Polym Chem 1999, 37, 1403. 11. Zhao, X.; Li, Y. F.; Zhang, S. J.; Shao, Y.; Wang, X. L. Polymer 2007, 48, 5241. 12. Wang, C. Y.; Li, G.; Jiang, J. M. Polymer 2009, 50, 1709. 13. Chung, C. L.; Hsiao, S. H. Polymer 2008, 49, 2476. 14. Wang, J. H.; Li, N. W.; Zhang, F.; Zhang, S. B.; Liu, J. Polymer 2009, 50, 810. 15. Liaw, D. J.; Liaw, B. Y.; Su, K. L. J Polym Sci Part A: Polym Chem 1999, 37, 1997. 16. Yang, C. P.; Chen, Y. P.; Woo, E. M. Polymer 2004, 45, 5279. 17. Liu, Y.; Zhang, Y. H.; Guan, S. W.; Li, L.; Jiang, Z. H. Polymer 2008, 49, 5439. 18. Choi, H. S.; Chung, I. S.; Hong, K.; Park, C. E.; Kim, S. Y. Polymer 2008, 49, 2644. 19. Acierno, D.; Fresa, R.; Iannelli, P.; Vacca, P. Polymer 2000, 41, 4179. 20. Desrosiers, N.; Bergeron, J. Y.; Belletete, M.; Durocher, G.; Leclerc, M. Polymer 1996, 37, 4. 21. Lin, L. L.; Hong, J. L. Polymer 2000, 41, 4501. 22. Spiliopoulos, I. K.; Mikroyannidis, J. A. Macromolecules 1998, 31, 522. 23. Chen, K. C.; Chen, X. B.; Yaguchi, K.; Endo, N.; Higa, M.; Okamoto, K. I. Polymer 2009, 50, 510. 24. Savard, O.; Peckham, T. J.; Yang, Y.; Holdcroft, S. Polymer 2008, 49, 4949. 25. Jung, J. C.; Park, S. B. J Polym Sci Part A: Polym Chem 1996, 34, 357. 26. Liu, Y. L.; Tsai, S. H. Polymer 2002, 43, 5757. 27. Wang, C. S.; Shieh, J.Y.; Sun Y. M. J Appl Polym Sci 1998, 70, 1959. 28. Sun, Y. M.; Hung, Y. C.; Wang, C. T. J Appl Polym Sci 2002, 85, 2367. 29. Shan, W. C.; Hsuan, L. C. Polymer 1999, 40, 4387. 30. Wang, C. S.; Lin, C. H.; Chen, C. Y. J Polym Sci Part A: Polym Chem 1998, 36, 3051. 31. Lin, C. H.; Lin, C. H. J Polym Sci Part A: Polym Chem 2007, 45, 2897. 32. Liou, G. S.; Hsiao, S. H. High Perform Polym 2001, 13, S137. 33. Liou, G. S.; Hsiao, S. H. J Polym Sci Part A: Polym Chem 2002, 40, 459. 34. Banerjee, S.; Palit, S. K.; Maiti, S. J Polym Sci Part A: Polym Chem 1994, 32, 219. 35. Liu, Y. L.; Hsiue, G. H.; Lan, C. W.; Kuo, J. K.; Jeng, R. J.; Chiu, Y. S. J Appl Polym Sci 1997, 63, 875. 36. Jeong, K. U.; Kim, J. J.; Yoon, T. H. Polymer 2001, 42, 6019. 37. Delaviz, Y.; Gungor, A.; Mcgrath, J. E.; Gibson, H. W. Polymer 1993, 34, 210. 38. Meyer, G. W.; Pak, S. J.; Lee, Y. J.; Mcgrath, J. E. Polymer 1995, 36, 2303.zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/3723-
dc.description.abstract本論文分成二個部分,第一部份在探討含磷二胺所衍生的新型芳香族polyetherimides (PEIs)之合成與性質。一種新型含磷二胺(3) 是由含磷二酚(1) 和1-fluoro-4-nitrobenzene 用低成本的K2CO3做為觸媒來進行芳香親核取代反應,生成含磷二硝(2) 後,再以氫氣和Pd/C 催化還原反應來得到。而一系列新型的芳香族 PEIs (5系列),是由含磷二胺(3) 與不同的芳香族二酸酐溶於DMAc,經由熱閉環法聚縮合製得。所得到PEIs (5系列) 表現出柔韌性和可撓性且具有優良的有機溶解性、玻璃轉移溫度 (Tg 270-304 ℃) 和熱安定性 (Td 5 wt % at 455-460 ℃) 及有低的熱膨脹係數 (47-51 ppm/ ℃)。 第二部分探討含磷二胺所衍生的新型芳香族polyimides (PIs)之合成與性質。新型含磷二胺(13) 是由9,10-dihydro-9-oxa-10- phosphaphenanthrene 10-oxide (DOPO)和4-nitrobenzaldehyde 進行親核性加成得到帶有拉電子基的NO2 (11),再進行還原反應來得到帶有推電子基的NH2 (12),最後再藉由親電子取代反應來獲得。之後再將新型的含磷二胺(13)與不同的二酸酐聚縮合製得PIs (14系列)。將所得到PIs (14系列) 與商業化不含磷二胺 (4,4’-diaminodiphenyl methane,DDM) 所合成出的PIs (17系列) 進行比較,當結構上導入巨大的磷基側鏈時,表現出高溶解性、高玻璃轉移溫度 (Tg 310-390 ℃)、 高熱安定性 (Td 5 wt % at 488-540 ℃) 及低熱膨脹係數 (46-58 ppm/ ℃)。zh_TW
dc.description.abstractThis investigation is divided into two parts. The first part is the discussion of the synthesis and properties of the derivatives from phosphorus-containing diamine, the new type of aromatic polyetherimides (PEIs). The new type of phosphorus-containing diamine (3) was prepared though the nucleophilic aromatic substitution reaction of phosphorus-containing diol (1) and 1-fluoro-4- nitrobenzene using the inexpensive K2CO3 as catalyst, followed by H2 reduction of the dinitro intermediate. A series of new type of aromatic PEIs (5 series) were made of phosphorus-containing diamine (3) with various aromatic dianhydrides in DMAc, followed by thermal imidization. The obtained PEIs (5 series) exhibit good flexibility, good organo-soluble, good glass transition temperature (Tg 270-304 ℃), good thermal stability (Td 5 wt % at 455-460 ℃) and low coefficient of thermal expansion (47-51 ppm/ ℃). The second part is the discussion of the synthesis and properties of the derivatives from phosphorus-containing diamine, the new type of aromatic polyimides (PIs). A new type of phosphorus-containing diamine (13) was made of 9,10- dihydro-9-oxa-10-phosphaphenanthrene 10-oxide (DOPO) and 4-nitrobenzaldehyde. A nucleophilic addition reaction was brought about to produce NO2 (11) with electron-withdrawing group, and then the reduction reaction was executed to obtain NH2 (12) with electron-donating group; finally, the product was made via electrophilic substitution reaction. Furthermore, we used the new type of phosphorus-containing diamine (13) with various dianhydrides to synthesize PIs (14 series) via polycondensation reaction. The PIs (14 series) were compared with the commercialized PIs (17 series) prepared from non-phosphorus diamine (4,4'- diaminodiphenyl methane,DDM), we found that, as the bulky biphenylene phosphinate pendant was incorporated into the structures, the products exhibited high solubility, high glass transition temperature (Tg 310-390 ℃), good thermal stability (Td 5 wt % at 488-540 ℃) and low coefficient of thermal expansion (46-58 ppm/ ℃).en_US
dc.description.tableofcontents中文摘要 i 英文摘要 ii 總目錄 iv 表目錄 viii 流程圖目錄 ix 圖目錄 x 第一章 緒論 1 第二章 原理與文獻回顧 2 第三章 實驗 5 3-1 藥品 5 3-2 單體之合成 7 3-2-1 單體(2)之合成7 3-2-2 單體(3)之合成8 3-3 聚合物之合成9 3-3-1 Polyetherimides (5a-d)之合成9 3-4 單體之合成10 3-4-1 單體(7)之合成10 3-4-2 單體(8)之合成11 3-5 聚合物之合成12 3-5-1 Polyetherimides(10a-d)之合成12 3-6 單體之合成13 3-6-1 單體(11)之合成13 3-6-2 單體(12)之合成14 3-6-3 單體(13)之合成15 3-7 聚合物之合成16 3-7-1 Polyimides (14a-d)之合成16 3-8 聚合物之合成17 3-8-1 Polyimides (17a-d)之合成17 3-9 儀器及測試方法18 第四章 結果與討論20 4-1 單體(2-3)之合成20 單體(2)的合成與特性20 NMR鑑定20 DSC鑑定33 低解析MASS鑑定34 高解析MASS鑑定35 單體(3)的合成與特性36 NMR鑑定36 低解析MASS鑑定42 高解析MASS鑑定43 FTIR鑑定44 4-2 單體(7-8)之合成45 單體(7)的合成與特性45 NMR鑑定45 DSC鑑定49 低解析MASS鑑定50 高解析MASS鑑定51 單體(8)的合成與特性52 NMR鑑定52 DSC鑑定56 低解析MASS鑑定57 高解析MASS鑑定58 FTIR鑑定59 4-3 含磷與不含磷Polyetherimides之合成60 Polyetherimides 5與 10 的合成與特性60 GPC鑑定61 NMR鑑定62 IR鑑定65 溶解度鑑定66 X-ray鑑定67 薄膜性質與熱性質鑑定68 熱安定性鑑定72 4-4 單體(11-13)之合成76 單體(11)的合成與特性76 NMR鑑定76 低解析MASS鑑定81 高解析MASS鑑定82 單體(12)的合成與特性83 NMR鑑定83 低解析MASS鑑定88 高解析MASS鑑定89 單體(13)的合成與特性90 NMR鑑定90 DSC鑑定95 低解析MASS鑑定96 高解析MASS鑑定97 FTIR鑑定98 4-5 含磷與不含磷Polyimides之合成99 Polyimides 14與 17 的合成與特性99 GPC鑑定.100 IR鑑定100 溶解度鑑定101 X-ray鑑定102 薄膜性質與熱性質鑑定103 熱安定性鑑定107 第五章 結論111 第六章 參考文獻112zh_TW
dc.language.isoen_USzh_TW
dc.publisher化學工程學系所zh_TW
dc.relation.urihttp://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-0608200916233100en_US
dc.subjectSolubilityen_US
dc.subject可溶性zh_TW
dc.subjectpolyetherimidesen_US
dc.subjectpolyimidesen_US
dc.subject聚醚醯亞胺zh_TW
dc.subject聚醯亞胺zh_TW
dc.title新型可溶性聚醚醯亞胺和聚醯亞胺之合成與特性zh_TW
dc.titleSynthesis and Characterization of New Solubility Polyetherimides and Polyimides.en_US
dc.typeThesis and Dissertationzh_TW
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeThesis and Dissertation-
item.cerifentitytypePublications-
item.fulltextno fulltext-
item.languageiso639-1en_US-
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