Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/3832
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dc.contributor李榮和zh_TW
dc.contributor詹立行zh_TW
dc.contributor.advisor鄭如忠zh_TW
dc.contributor.author陳遠鵬zh_TW
dc.contributor.authorChen, Yuan-Pengen_US
dc.contributor.other中興大學zh_TW
dc.date2011zh_TW
dc.date.accessioned2014-06-06T05:32:53Z-
dc.date.available2014-06-06T05:32:53Z-
dc.identifierU0005-2008201011251400zh_TW
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dc.identifier.urihttp://hdl.handle.net/11455/3832-
dc.description.abstract本研究針對共軛高分子HOMO能階進行調控,克服高分子太陽能電池在氧化穩定性與開路電壓的問題。透過Stille與Suzuki coupling共聚反應合成一系列P型共軛高分子,皆可溶於一般有機溶劑並具備良好熱穩定性。由光譜與電化學性質得知,共軛高分子側鏈導入三苯胺可使材料吸收光譜增寬,並有效調整HOMO能階。將材料製成元件後進行光伏特性質量測,高分子主鏈因含未取代共軛單元,使太陽能電池獲得較佳的開路電壓。觀察材料與PC61BM混摻型態顯示,主鏈因含未取代共軛單元,能提供有效空間使共軛高分子與PC61BM混摻相容性提升。其中主鏈含二苯乙烯且側鏈含三苯胺之共軛高分子與PC61BM 1:1 (w/w) 混摻之太陽能電池開路電壓為0.83 V,光電轉換效率為0.48 %。zh_TW
dc.description.abstractP-type conjugated polymers containing pendant triphenylamines were synthesized via Stille and Suzuki coupling reactions. All polymers exhibited good solubility in common organic solvents and stable thermal properties. The introduction of triphenylamines as side chains would broaden the absorption of solar spectra and modulate the HOMO levels of polymers. With the presence of unsubstituted conjugated moieties in main chain, the HOMO level was lowered. Consequently, a larger open circuit voltage of polymer-based solar cell was obtained. Sufficient free volume was provided by unsubstituted conjugated moieties in the polymer main chain, which improved the miscibility of bulk heterojunction observed by an optical microscope. Our preliminary results exhibited a power conversion efficiency of 0.48 % and a Voc of 0.83 V under illumination AM 1.5, 100 mW/cm2. This suggests that the conjugated polymer comprising pendant triphenylamines are potentially useful for solar cell applications.en_US
dc.description.tableofcontents誌謝 I 中文摘要 II 英文摘要 III 圖目錄 VI 表目錄 VIII 第一章 緒論 1 1.1前言 1 1.2太陽能的獨特優點 1 1.3太陽能發展歷史與有機太陽能電池的優勢與分類 1 1.4高分子太陽能電池工作原理 4 1.5高分子太陽能電池結構演進 5 1.5.1 單層結構 (single layer structure) 5 1.5.2 雙層異質結面結構 (bilayer heterojunction structure) 5 1.5.3 混摻異質接面結構 (bulk heterojunction structure, BHJ) 6 第二章 文獻回顧與研究動機 9 2.1材料能階與開路電壓之關係 9 2.2降低材料HOMO能階 10 2.3調整材料能隙 10 2.4提升材料載子傳輸能力 12 2.5增進材料與碳球衍生物的相容性 13 2.6增寬光譜吸收範圍 13 2.7研究動機 14 第三章 實驗部份 16 3.1藥品與溶劑 16 3.2儀器 18 3.3 合成 20 3.3.1單體合成 22 3.3.2共軛高分子聚合 30 第四章 結果與討論 34 4.1共軛高分子基本特性 34 4.1.1分子量 34 4.1.2溶解性 34 4.1.3熱性質 34 4.2光學特性 36 4.2.1 紫外光-可見光光譜 (UV-vis ) 36 4.3電化學特性 47 4.4主動層型態分析 51 4.4.1原子力顯微鏡 (AFM) 51 4.4.2偏光顯微鏡 (POM) 53 4.5元件光伏特性質分析 55 4.5.1共軛高分子基本元件光伏特性質探討 55 4.5.2 共軛高分子與PC61BM不同混摻比例之光伏特性質探討 56 4.5.3元件經熱處理後對光伏特性質的影響 57 第五章 結論 60 第六章 參考文獻 61 附錄 66zh_TW
dc.language.isoen_USzh_TW
dc.publisher化學工程學系所zh_TW
dc.relation.urihttp://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-2008201011251400en_US
dc.subjectTriphenylamineen_US
dc.subject三苯胺zh_TW
dc.subjectpolymer solar cellsen_US
dc.subjectHOMOen_US
dc.subjectVocen_US
dc.subject太陽能電池zh_TW
dc.subject能階zh_TW
dc.subject開路電壓zh_TW
dc.title側鏈含三苯胺之P型共軛高分子合成及其在太陽能電池應用與光電性質探討zh_TW
dc.titleSynthesis and Photovoltaic Properties of a Series of Triphenylamine Pendant Containing P-type Conjugated Polymers.en_US
dc.typeThesis and Dissertationzh_TW
item.languageiso639-1en_US-
item.openairetypeThesis and Dissertation-
item.cerifentitytypePublications-
item.grantfulltextnone-
item.fulltextno fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
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