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標題: 固定化螢光染料丹磺醯氯於再生纖維素薄膜及其對芳香族硝基化合物螢光感測性質之研究
mmobilization of 5-(dimethylamino)naphthalene-1- sulfonyl chloride on regenerated cellulose membranes and their sensing properties for aromatic nitro compounds
作者: 于淳安
Yu, Chun-An
關鍵字: 再生纖維素薄膜;Regenerated cellulose membrane;丹磺醯氯;乙二醇二縮水甘油醚;螢光感測器;5-(Dimethylamino)naphthalene-1-sulfonyl chloride;Ethylene glycol diglycidyl ether;Fluorescent sensor
出版社: 化學工程學系所
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本研究利用再生纖維素薄膜做為基材,對其表面之氫氧基以化學方法固定化螢光分子,達到做為螢光偵測器的應用。本研究將螢光分子加上延伸臂固定化於再生纖維素薄膜表面,成功地對其表面改質並進行螢光感測的應用。實驗選用5-(二甲氨基)萘-1-磺醯氯(丹磺醯氯)做為螢光染料,因其具有強的螢光發光性、敏感性及大的史托克位移,並對氫氧基有高度反應性。另以乙二醇二缩水甘油醚(EGDGE)做為延伸臂,一方面可降螢光分子與薄膜表面非均相反應的障礙,另可增加OH基之數量以提高可反應點。成功改質後的再生纖維素薄膜分別以ATR-FTIR、螢光光譜儀、共軛交螢光顯微鏡做定性及半定量的分析,以求出化學反應改質的最佳條件。本研究發現接有螢光染料的纖維素薄膜可以有效針對含有硝基的芳香族化合物做低濃度2~10 ppm的感測,如4-nitrophenol, 4-nitrobenzoic acid 、4-nitrodiphenyl ether與nitrobenzene。與其他感測器相較具有快速、測量方式簡易等優點。

In this study, fluorescent dye was coupled onto the surface of regenerated cellulose membrane to form a fluorescent sensor. 5-(Dimethylamino) naphthalene-1-sulfonyl chloride (DANS-Cl) was used because of its high fluorescent intensity, sensitivity, and big Stokes shift. Ethylene glycol diglycidyl ether (EGDGE) was adopted as the spacer arm for connecting the OH groups of membrane and the sulfochloride group of DANS-Cl, as well as decreasing the steric effect. The DANS-Cl coupled membranes were characterized by ATR-FTIR, fluorescence spectrophotometer, and laser scanning confocal microscope. The fluorescent quenching results show that the modified membranes are sensitive to the presence of 4-nitrophenol, 4-nitrobenzoic acid, 4-nitrodiphenyl ether and nitrobenzene. The Stern-Volmer plots are found to be linear in the concentration range from 2 to 10 ppm.
其他識別: U0005-1708201112423400
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