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標題: Enhanced photovoltaic performance of quasi-solid-state dye-sensitized solar cells via incorporating quaternized ammonium iodide-containing conjugated polymer into PEO gel electrolytes
作者: Lee, Rong-Ho
Cheng, Tun-Fang
Chang, Jhih-Wei
Ho, Jhu-Heng
關鍵字: Dye-sensitized solar cell;Conjugated polymer electrolyte;Polymer gel electrolyte;Photovoltaic property;Photoconversion efficiency
出版社: Springer
Project: Colloid and Polymer Science, Volume 289, Issue 7, Page(s) 817-829.
In this study, a series of gel electrolytes prepared from blends of alternating conjugated polymer electrolytes (CPEs)/poly(ethylene oxide) (PEO) were developed for use in quasi-solid-state dye-sensitized solar cells (DSSCs). The alternating CPEs poly(N-(3'-((N,N-dimethyl)-N-ethylammonium)propyl)-3,6-carbazole)-alt-(9,9-dioctyl-2,7-fluorene)diiodide, poly(N-(3'-((N,N-dimethyl)-N-ethylammonium)propyl)-3,6-carbazole)-alt-(9,9-bis(2-(2-methoxyethoxy)ethyl)-2,7-fluorene)diiodide (MPCFO-E), and poly(N-(3'-((N,N-dimethyl)-N-ethylammonium)propyl)-3,6-carbazole)-alt-(siloxane substituted-2,7-fluorene)diiodide (MPCFS-E) were synthesized through copolymerization of carbazole units (featuring quaternized ammonium iodide groups) and fluorene units featuring flexible side chains (9,9-dioctylfluorene, ethylene oxide-substituted fluorene, and siloxane-substituted fluorene, respectively). The MPCFO-E/PEO-based and MPCFS-E/PEO-based DSSCs exhibited lower electrochemical resistances, superior photovoltaic (PV) properties, and improved PV stabilities relative to those of the corresponding PEO-based DSSC. Among the studied systems, the DSSC based on the MPCFO-E (0.5 wt.%)/PEO blend electrolyte exhibited the best PV performance, with a short current density of 4.97 mA cm(-2) and a photoenergy conversion efficiency of 1.17%.
ISSN: 0303-402X
DOI: 10.1007/s00396-011-2397-9
Appears in Collections:化學工程學系所

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