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標題: Development of an aromatic triamine-based flame-retardant benzoxazine and its high-performance copolybenzoxazines
作者: Chang, C.W.
Lin, C.H.
Lin, H.T.
Huang, H.J.
Hwang, K.Y.
Tu, A.P.
關鍵字: Benzoxazine;Thermosets;Flame retardancy;High-T(g);ring-opening polymerization;epoxy-resins;thermal characterization;curing behavior;bisphenol-a;polybenzoxazines;phosphorus;monomers;nanocomposites;composites
Project: European Polymer Journal
期刊/報告no:: European Polymer Journal, Volume 45, Issue 3, Page(s) 680-689.
An aromatic triamine-based flame-retardant benzoxazine (3), which could not be prepared by the traditional approaches, was successfully prepared by a three-step procedure. The first step is the condensation of 2-hydroxybenzaldehyde with an aromatic triamine, forming intermediate (1) with an imine linkage. The second step is the reduction of the imine linkage by sodium borohydride, resulting in intermediate (2) with a secondary amine linkage. The third step is the ring closure condensation of (2), leading to benzoxazine (3). The structures of (1-3) were confirmed by IR, high-resolution mass, (1)H and (31)P NMR spectra. Benzoxazine (3) was copolymerized with commercial benzoxazines. According to the measurements, thermal properties, flame retardancy, dimensional stability of commercial polybenzoxazines were significantly improved via the incorporation of (3). (C) 2009 Elsevier Ltd. All rights reserved.
ISSN: 0014-3057
DOI: 10.1016/j.eurpolymj.2008.12.020
Appears in Collections:化學工程學系所

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