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標題: Effect of photoelectron on the condensed film of poly(oxypropylene)amine intercalated silicates
作者: Lee, R.J.
Cheng, W.T.
Lin, J.J.
關鍵字: photoelectron;organo-silicate;poly(oxypropylene)amine;polymer melt intercalation;modified layered silicates;clay;nanocomposites;model;gels
Project: Journal of Photopolymer Science and Technology
期刊/報告no:: Journal of Photopolymer Science and Technology, Volume 21, Issue 1, Page(s) 15-19.
In this paper, photoelectron effect is applied to describe the reaction mechanism of macroscopic orderly stacking new crystalline from the poly(oxypropylene)amine modified clays. With X-ray fluorescent irradiates' the condensed film of poly(oxypropylene)amine intercalated smectite silicates, a special inhomogeneous Si photoelectron (102.1 electron volts) concentration pattern was revealed. Silicone with shifted electron binding energy on the surface of the organo-silicates causes the photoelectron energy differentiated. Analysis of the FTIR vibration spectrums show no new chemical bonding assigned to the organo-silicate condensation: It is proposed the radius of ionic outer shell of silicone was altered as the poly(oxypropylene)amine intercalated montmorillonite proceeding a organo-mineral polymerization by self assembly process. Optical polarized microscope and X-ray diffraction pattern also confirmed the transformation of random particulate to a special nematic texture of organo-clay hybrid polymer.
ISSN: 0914-9244
DOI: 10.2494/photopolymer.21.15
Appears in Collections:化學工程學系所

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