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|標題:||Effect of photoelectron on the condensed film of poly(oxypropylene)amine intercalated silicates||作者:||Lee, R.J.
|關鍵字:||photoelectron;organo-silicate;poly(oxypropylene)amine;polymer melt intercalation;modified layered silicates;clay;nanocomposites;model;gels||Project:||Journal of Photopolymer Science and Technology||期刊/報告no：:||Journal of Photopolymer Science and Technology, Volume 21, Issue 1, Page(s) 15-19.||摘要:||
In this paper, photoelectron effect is applied to describe the reaction mechanism of macroscopic orderly stacking new crystalline from the poly(oxypropylene)amine modified clays. With X-ray fluorescent irradiates' the condensed film of poly(oxypropylene)amine intercalated smectite silicates, a special inhomogeneous Si photoelectron (102.1 electron volts) concentration pattern was revealed. Silicone with shifted electron binding energy on the surface of the organo-silicates causes the photoelectron energy differentiated. Analysis of the FTIR vibration spectrums show no new chemical bonding assigned to the organo-silicate condensation: It is proposed the radius of ionic outer shell of silicone was altered as the poly(oxypropylene)amine intercalated montmorillonite proceeding a organo-mineral polymerization by self assembly process. Optical polarized microscope and X-ray diffraction pattern also confirmed the transformation of random particulate to a special nematic texture of organo-clay hybrid polymer.
|Appears in Collections:||化學工程學系所|
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