Please use this identifier to cite or link to this item:
標題: Preparation of epoxy resin/silica hybrid composites for epoxy molding compounds
作者: Liu, Y.L.
Lin, Y.L.
Chen, C.P.
Jeng, R.J.
關鍵字: nanocomposites;silicas;sol-gel process;organic-inorganic nanocomposites;thermal-stability;thermogravimetric analysis;silica hybrid;clay nanocomposites;polymer;flame;polystyrene;resistance
Project: Journal of Applied Polymer Science
期刊/報告no:: Journal of Applied Polymer Science, Volume 90, Issue 14, Page(s) 4047-4053.
Phenolic novolac/silica and cresol novolac epoxy/silica hybrids were prepared through in situ sol-gel reaction of tetraethoxysilane (TEOS). The formed hybrids were utilized as a curing agent and an epoxy resin in epoxy curing compositions, respectively. Via the two-step preparation route, the resulting epoxy resin/silica hybrid nanocomposites exhibited good thermal stability, high glass transition temperatures, and low coefficients of thermal expansion. High condensation degree of the condensed silica was observed with a high content of siloxane bridges, p > 85%, measured by Si-29 NMR. The two-step route also provides feasibility of preparation of epoxy resin/silica hybrid nanocomposites compatible with the current processes of manufacturing of epoxy molding compounds. (C) 2003 Wiley Periodicals, Inc.
ISSN: 0021-8995
DOI: 10.1002/app.13159
Appears in Collections:化學工程學系所

Show full item record

Google ScholarTM




Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.