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標題: | Enhancing the glass-transition temperature of polyimide copolymers containing 2,2 '-bipyridine units by the coordination of nickel malenonitriledithiolate | 作者: | Chen, C.T. 鄭如忠 Hsu, T.S. Jeng, R.J. Yeh, H.C. |
關鍵字: | polyimide;bipyridine;coordination complexes;nickel;glass-transition;temperature;nonlinear-optical applications;thermal-stability;complexes;design | Project: | Journal of Polymer Science Part a-Polymer Chemistry | 期刊/報告no:: | Journal of Polymer Science Part a-Polymer Chemistry, Volume 38, Issue 3, Page(s) 498-503. | 摘要: | Polyimide copolymers containing 2,2'-bipyridine were synthesized and characterized. The glass-transition temperatures (T-g's) of the polymers ranged from 260 to 300 degrees C. In contrast to most known organic chromophore-containing polyimides, the polyimide copolymers in this study showed elevated T-g's (270-320 degrees C) after coordination with nickel malenonitriledithiolate inorganic chromophores. (C) 2000 John Wiley & Sons, Inc. |
URI: | http://hdl.handle.net/11455/41836 | ISSN: | 0887-624X | DOI: | 3.0.co;2-p>10.1002/(sici)1099-0518(20000201)38:3<498::aid-pola15>3.0.co;2-p |
Appears in Collections: | 化學工程學系所 |
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