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|標題:||Thermally stable NLO poly(amide-imide)s via sequential self-repetitive reaction||作者:||Chang, H.L.
|關鍵字:||poly(amide-imide);sequential self-repetitive reaction;NLO;nonlinear-optical materials;2-dimensional carbazole chromophore;enhanced temporal stability;alkoxysilane dye;electrooptic;coefficients;thermoset polyurethane;polymers;polyimides;progress;films||Project:||Polymer||期刊/報告no：:||Polymer, Volume 48, Issue 7, Page(s) 2046-2055.||摘要:||
A series of thermally stable side-chain second-order nonlinear optical (NLO) poly(amide-imide)s via sequential self-repetitive reaction (SSRR) have been developed. This SSRR is based on carbodiimide (CDI) chemistry. Three difunctional azo chromophores (DR19, NDPD and DNDA) were, respectively, reacted with excessive amount of 4,4 '-methylene-diphenylisocyanate (MDI) to form poly-CDI, and subsequently trimellitic anhydride (TMA) was added to obtain an intermediate, poly(N-acylurea). Poly(N-acylurea) exhibits excellent organosolubility, which enables the fabrication of high quality optical thin films. Moreover, its moderate glass transition temperature (T-g) characteristic allows the NLO-active polymer to exhibit high poling efficiency. After in situ poling and curing process, N-acylurea moieties were converted to amide-imide structures via SSRR, and the T(g)s of the polymers were elevated significantly up to 70 degrees C higher than that of the poly-CDI sample. Electro-optical coefficients, r(33) of about 5.2-25.2 pm/V at 830 nm were obtained. Good temporal stability (80 degrees C) and waveguide optical losses (3.8-6.6 dB/ cm at 830 nm) were also obtained for these polymers. (c) 2007 Elsevier Ltd. All rights reserved.
|Appears in Collections:||化學工程學系所|
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