Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/4305
標題: 奈米銀於染料敏化太陽能電池效率之研究
Investigation of efficiency relates nano silver of Dye-sensitized Solar Cell
作者: 林哲丞
Lin, Je-Cheng
關鍵字: 染料敏化太陽能電池;Dye-sensitized solar cells;二氧化鈦;奈米銀;表面電漿共振;真空注入浸泡;TiO2;nano silver;surface plasmon resonance;Vacuum soaking immersing
出版社: 精密工程學系所
引用: [1]http://www.jpl.nasa.gov/news/news.php?release=2012-376, NASA [2]http://e-info.org.tw/column/eccpda/2004/ec04052501.htm,環境資訊中心 [3]http://web3.moeaboe.gov.tw/ECW/populace/content/ContentLink.aspx?menu_id=137, 經濟部能源局年報 [4] Martin, A. G., Keith, E., Yoshihiro, H., Wilhelm, W. and Ewan, D.D., “Solar cell efficiency tables (version 41),” vol. 21, no. 1, pp. 1-11, 2013. [5]Tsubomura, H., Matsumura, M., Nomura, Y. and Amamiya, T., “Dye sensitized Zinc oxide Aqueous electrolyte Platinum photocell,” Nature, vol. 261, pp. 402-403, 1976. [6] Oregan, B. and Gratzel, M., ” A low-cost, high-efficiency solar-cell based on dye-sensitied colloidal TiO2 films ,” vol. 353, no. 6346, pp. 731-740, 1991. [7]賴炤銘,李錫隆,奈米材料的特殊效應與應用,Chemistry, vol. 61, No. 4, pp. 585-597, 2003. [8]郭清癸, 黃俊傑, 牟中原, “金屬奈米粒子的製造,” 物理雙月刊,vol.23, no.6, pp.614-624, 1999. [9] Mafune, F., Kohno, J. Y., Takeda, Y., and Kondow, T., “Formation and size control of sliver nanoparticles by laser ablation in aqueous solution,” Journal of Physical Chemistry, vol. 104, no. 39, pp. 8333-8337, 2000. [10] Mafune, F., Kohno, J. Y., Takeda, Y., and Kondow, T., “Full physical preparation of size-selected gold nanoparticles in solution: Laser ablation and laser-induced size control,” Journal of Physical Chemistry, vol. 106, no. 31, pp. 7575-7577, 2002. [11]Templeton, A. C., Wuelfing, W. P. and Murray, R. W., “Monolayer-Protected Cluster Molecules,” Acc Chem Res, vol. 33, no. 27, 2000. [12]Chou, C.-S., Yang, R.-U., Yeh, C.-K. and Lin, Y.-J., “Preparation of TiO2/Nano-metal composite particles and their applications in dye-sensitized solar cells,” Power Technology, vol. 194, pp. 95-105, 2009. [13]呂晃志, 奈米銀(nano silver), 逢甲大學奈米科技研究中心, 2007。 [14]吳民耀、劉威志, 表面電漿子理論與模擬, 物理雙月刊, vol. 28, no. 2, pp. 486-496, 2006. [15]Bohren, C. and Huffman, D., “Absorption and Scattering of Light by Small Particles,” , Nature, vol. 306, no.5943, pp.625, 1983. [16]陳泊睿, 利用化學處理對染料敏化太陽能電池效率之影響,國立東華大學光電工程研究所碩士論文, 2010。 [17] Park, N.-G., Lagemaat, V. D. and Frank, A. J., “Comparison of dye-sensitized rutile and anatase based TiO2 solar cells,” Journal of Physical Chemistry, vol. 104, no. 38, pp. 8989-8994, 2000. [18]簡國明、洪長春、吳典熹、王永銘、藍怡平, “奈米二氧化鈦專利地圖及分析,” 行政院國家科學委員會, 2003. [19]彭懷夫, 中孔性二氧化鈦薄膜於染料敏化太陽能電池之應用, 國立東華大學化學研究所碩士論文,2004。 [20] Gratzel, M., “Photoelectrochemical cells,” Nature, vol. 414, pp. 338-344, 2001. [21] Wang, Z. S., Kawauchi, H., Kashima, T. and Arakawa, H., “Significant influence of TiO2 photoelectrode morphology on the energy conversion efficiency of N719 dye-sensitized solar cell,” Coordination Chemistry Reviews, vol. 248, pp.1381-1389, 2004. [22] Ito, S., Zakeeruddin, S. M., Robin, H. B., Liska, P., Charvet, R., Comte, P., Nazeeruddin, M. K., Pechy, P., Takata, M., Miura, H., Uchida, S., and Gratzel, M., “High-Efficiency Organic-Dye-Sensitized Solar Cells Controlled by Nanocrystalline-TiO2 Electrode Thickness,” Advanced Materials, vol. 18, no. 9, pp. 1201-1205, 2006. [23] Agrell, H.G., Lindgren, J., Hagfeldt, A., ” Degradation mechanisms in a dye-sensitized solar cell studied by UV-VIS and IR spectroscopy,” Solar Enrgy, vol. 75, no. 2, pp. 169-180, 2003. [24]David B, Menzies, Qing Dai, Yi.Bing. Cheng, P.Simon, Leone Spiccia”One-step microwave calcination of ZrO2-coated TiO2 electrodes for use in dye-sensitized solar cells.” Chimie, no.9 pp.713-716, 2006. [25]Kalyanasund, K.and Gratzel, M., :Applications of functionalized transition metal complexes in photonic and optoetyonic,”Coordination Chemistyy Reviews, no. 177, pp.347, 1988. [26] Wolfbauer, G., Bond, A. M., Eklund, J. C., MacFarlane, D. R., “A channel flow cell system specifically designed to test the efficiency of redox shuttles in dye sensitized solar cells,” Solar Energy Materials and Solar Cells, vol.70, no.1 pp. 85-101, 2001. [27] Gratzel, M., “Recent Advances in Sensitized Mesoscopic Solar Cells,” Accounts of Chemical Research, vol. 11, no. 11, pp. 1788-1798, 2009. [28]楊鈺貞, 利用溶膠-凝膠法來改善二氧化鈦薄膜工作電極應用於染料敏化太陽能電池, 長庚大學光電工程研究所碩士論文, 2010。 [29] http:// research.nchu.edu.tw/topnchu/index_05.aspx, 中興大學, 貴重儀器中心 [30] http://www.chem.chna.edu.tw/?.p=Hjoo&.hl=zh-tw, 嘉南藥理科技大學, 醫藥化學系 [31] Kumar, K. D., “Rapid and green synthesis of silver nanoparticles using the leaf extracts of parthenium hysterophorus:A novel biological approach,” International Research Journal of Pharmacy, vol. 3, no. 2, pp. 169-173, 2012.
摘要: 
本論文主要著重於兩部分,第一部分為在TiO2二氧化鈦溶液和染料中加入奈米銀溶液,利用奈米銀本身的特殊光電性質所產生的表面電漿共振,用來提升染料分子吸光的效率,以增加染料敏化太陽能電池的光電轉換效率,第二部分則是使用刮刀塗佈的方式來進行工作電極的製作,當中包含TiO2 sol-gel和P25漿料兩種不同溶液,並利用新型的真空注入浸泡染料方式,抽除TiO2二氧化鈦薄膜孔隙中得空氣分子,來提升吸附效率和縮短浸泡時間。
本研究結果,在TiO2二氧化鈦溶液中添加奈米銀所製成的染料敏化太陽能電池,確實能增加其光電轉換率,真空注入浸泡方式也確實較一般浸泡方式有效率,証明表面電漿共振效應和真空設備設計的效用。

This research was focusing on two section, The first section was adding nano silver solution into TiO2 sol-gel. Use the surface plasmon resonance generating by photovoltaic characteristics of nano silver to enhance the dye molecules absorbing efficiency and the efficiency of DSSCs. The second section was using doctor blade method to fabricate the working electrode by two different solution : TiO2 sol-gel and P25 paste. Vacuum air molecules out of the TiO2 films by using new vacuum soaking immersing method to enhance absorbing efficiency and shorten immersing time.
By the conclusions of this research, the DSSCs fabricate by adding nano silver solution into TiO2 sol-gel could enhance the photovoltaic transfer efficiency. The vacuum soaking immersing method was better than the original immersing method. Prove the utility of surface plasmon resonance and vacuum equipment design.
URI: http://hdl.handle.net/11455/4305
其他識別: U0005-2708201311333500
Appears in Collections:精密工程研究所

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