Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/4314
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dc.contributor薛英家zh_TW
dc.contributorIn-Cha Hsiehen_US
dc.contributor.author于明宏zh_TW
dc.contributor.authorYu, Ming-Hungen_US
dc.contributor.other精密工程學系所zh_TW
dc.date2013en_US
dc.date.accessioned2014-06-06T06:27:32Z-
dc.date.available2014-06-06T06:27:32Z-
dc.identifierU0005-1908201315483200en_US
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dc.identifier.urihttp://hdl.handle.net/11455/4314-
dc.description.abstract本研究中探討如何能快速有效使二氧化鈦薄膜吸附染料,由於二氧化鈦薄膜為多孔性且高比表面積之特性,故使染料能快速並有效吸收為染料敏化太陽能電池之重要課題,我們分為兩部份作探討:第一部份為製作二氧化鈦工作電極時,使用旋轉塗佈法與刮刀塗佈法,並搭配二氧化鈦溶膠凝膠與P25漿料之不同組合,量測其薄膜品質之優劣。第二部份為使用真空注入法增加染料吸收的效率,並使用了本實驗室自行改造之真空注入設備與萃盤,以不同支真空壓力與是否加溫之浸泡條件觀測染料吸收的結果。 本研究目的為改善染料對於二氧化鈦薄膜之吸附效率,使用不同量測與分析方法觀察各種條件對於元件之影響,以縮短製程時間與降低成本為首要課題。使用本實驗室自製之真空注入設備將染料注入二氧化鈦薄膜並加溫50℃浸泡一小時,其效率已超越常溫常壓下浸泡八小時之試片,因此可節省染料浸泡時間,達到成本降低之目的。zh_TW
dc.description.abstractThis researchprobed how to enhance TiO2 filmsabsorbing efficiency. It is important for DSSCs absorbing dye molecular quickly because of the porous TiO2 films. We probed this topic in two sections. First section, we use spin coating method and doctor blade method with TiO2 sol-gel and P25 paste for fabricating TiO2 working electrode and tested thin films quality. Second section, we use pore filling method toenhance dye absorbing efficiency. We use custom vacuum inject equipment and tray in different pressure and heating degree to obtain dye absorbing results. The researches were focus on enhancing TiO2 filmsabsorbing efficiency and using different method to measure the samples. The most important target was that to shorten fabrication time and cost down. The efficiency of sample immersing in 50℃for one hour by custom vacuum inject equipment was better than immersing in atmospheric pressureand 25℃ for 8 hours. So by using the equipment could save immersing time to cost down.en_US
dc.description.tableofcontents中文摘要 I ABSTRACT II 目錄 III 圖目錄 V 表目錄 VII 第一章緒論 1 1.1 前言 1 1.2 研究背景 4 1.3 研究動機 6 第二章文獻回顧與理論背景 7 2.1 染料敏化太陽能電池工作原理 7 2.2 染料敏化太陽能電池(DSSC)結構 8 2.2.1. 工作電極 9 2.2.2. 染料 12 2.2.3. 電解質 15 2.2.4. 對電極 16 2.3 染料敏化太陽能電池轉換效率理論 18 2.3.1. 太陽能電池之等效電路 18 2.3.2. 短路電流 (Short circuit current) 20 2.3.3. 開路電壓 (Open circuit voltage) 20 2.3.4. 填充因子 (Fill factor) 21 2.3.5. 能量轉換效率 (power conversionefficiency) 22 2.4 溶膠-凝膠法 22 2.4.6. 溶膠-凝膠法的概念 22 2.4.7. 溶膠-凝膠的反應製程原理 23 2.4.8. 溶膠-凝膠的反應製程步驟 24 第三章實驗介紹 26 3.1 實驗規劃 26 3.2 實驗流程 27 3.2.1. 玻璃基板製備 27 3.2.2. 製作二氧化鈦溶液 27 3.2.3. 製作二氧化鈦漿料 29 3.2.4. 製作TiO2二氧化鈦工作電極 29 3.2.5. 白金對電極製作 30 3.2.6. 熱回火製程 30 3.2.7. 染料配製 31 3.2.8. 真空法浸泡染料 31 3.2.9. 電池組裝 36 3.3 實驗設備及材料 37 3.3.1. 實驗氣體與材料 37 3.3.2. 實驗設備 38 3.3.3. 實驗工具 39 3.4 量測儀器 41 3.4.1. TiO2薄膜特性量測 41 3.4.2. 光電轉換效率量測 44 第四章結果與討論 45 4.1 薄膜特性分析 45 4.1.1. α-step之厚度分析 45 4.1.2. SEM分析 47 4.2 燒結結果之XRD分析 49 4.3 染料與工作電極特性分析 51 4.3.1. FT-IR分析 51 4.3.2. UV-VIS分析 52 4.4 光電轉換效率分析 54 第五章結論 58 第六章未來展望 59 參考文獻 60zh_TW
dc.language.isozh_TWen_US
dc.publisher精密工程學系所zh_TW
dc.relation.urihttp://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-1908201315483200en_US
dc.subject染料敏化太陽能電池zh_TW
dc.subjectdye-sensitized solar cellen_US
dc.subject溶膠凝膠法zh_TW
dc.subject二氧化鈦zh_TW
dc.subject染料zh_TW
dc.subject真空注入法zh_TW
dc.subjectsol-gel methoden_US
dc.subjecttitanium oxideen_US
dc.subjectdyeen_US
dc.subjectpore fillingen_US
dc.title染料敏化太陽能電池之製程效率研究zh_TW
dc.titleInvestigation of efficiency relates to process of Dye Sensitized Solar Cellen_US
dc.typeThesis and Dissertationzh_TW
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeThesis and Dissertation-
item.cerifentitytypePublications-
item.fulltextno fulltext-
item.languageiso639-1zh_TW-
item.grantfulltextnone-
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