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標題: 石墨烯薄膜製程之研究
Investigation of Thin Film Process of Graphene.
作者: 張肇恩
Chang, Zhao-En
關鍵字: 石墨烯;graphene;單層奈米碳管;導電膜;靜電吸附;自我組裝;single-walled carbon nanotubes;conductive thin film.
出版社: 精密工程學系所
引用: 1. Carpio, A., Bonilla, L. L., Juan, F. D. and Fernando, V., “Dislocations in graphene,” New Journal of Physics, vol. 10, no. 5, pp. 351-354, 2008. 2. Iijima, S., "Helical microtubules of graphitic carbon," Nature, vol. 354, pp. 56-58, 1991. 3. Geim, A. K. and Novoselov, K. S., "The rise of graphene," Nature Materials, vol. 6, pp. 183-191, 2007. 4. Suk, J. W., Kitt, A., Cral, W. and Swan, A. K., “Transfer of CVD-grown monolayer graphene onto arbitrary substrates,” American Chemical Society, vol. 5, pp. 1946-1952, 2011. 5. Penuelas, J., Ouerghi, A., Lucot, D. and Gierak, J., “Surface morphology and characterization of thin graphene films on SiC vicinal substrate,” American Chemical Society, vol. 65, no. 3, pp. 837-855, 2009. 6. Sikes, K. J., Jiang, Z., Klima, M., Fudenberg, G., Hone, J., Kim, P. and Stomer, H. L., “Ultrahigh electron mobility in suspended graphene,” Solid State Communications, vol. 146, pp. 351-355, 2008. 7. Ghosh, S., Bao, W., Nika, D. L., Subrina, S. Pokatilov, E. P., Lau, C. N. and Balandin, A. A., “Dimensional crossover of thermal transport in few-layer graphene,” Nature Materials, pp. 555-558, 2010. 8. The Royal Swedish Acandemy of Sciences, GRAPHENE, 2010. 9. Robinson, J. T., Burgess, J. S. and Junkermeier, C. E., “Properties of fluorinated graphene films,” Nano Letters, pp. 3001-3005, 2010. 10. Kelly, B. T., Physics of graphite, London: Imperial College Press, 1991. 11. Kim, Y. S., Kumar, K., Fisher, F. T. and Yang, E. H., “Out-of-plane growth of CNTs on graphene for supercapacitor applications,” Nanotechnology, pp. 553-557, 2012. 12. Stankovich, S., Piner, R. D., Nguyen, S. T. and Ruoff, R. S., “ Stable aqueous dispersions of graphitic nanoplatelets via the reduction of exfoliated graphite oxide in the presence of poly,” Journal of Materials Chemistry, vol. 16, pp. 155-158, 2006. 13. Stankovich, S., Piner, R. D., Nguyen, S. T. and Ruoff, R. S., “Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets,” Carbon, vol. 44, pp. 3342-3347, 2006. 14. 蘇清源,石墨烯氧化物之特性與應用前景,物理專文,163-167,2011. 15. Park, Y. T., Ham, A. Y. and Grunlan, J. C., "Heating and acid doping thin film carbon nanotube assemblies for high transparency and low sheet resistance," Journal of Materials Chemistry, vol. 21, pp. 363-368, 2011. 16. Shin, C. J., Sharma, R., Han, J. H., Jin, Z., Shangchao, L. and Strano, M. S., “Bi- and trilayer graphene solutions,” Nature Nonotechnology, vol. 6, pp. 439-445, 2011. 17. Hernandez, Y., Nicolosi, V. and Lotya, M., “High-yield production of graphene by liquid phase exfoliation of graphite,” Nature Nanotech, vol. 3, pp. 563-568, 2008. 18. Decher, G., "Fuzzy Nanoassemblies : Toward Layered Polymeric Multicomposites," Science, vol. 277, no. 5330, pp. 1232-1237, 1997. 19. Lee, C. J., Park, J. H. and Park, J., "Synthesis of bamboo-shaped multiwalled carbon nanotubes using thermal chemical vapor deposition," Chemical Physics Letters, vol. 323, pp. 560-565, 2000. 20. Li, X. S., Cai, W. W., Kim, S. and An, J., “Large-area synthesis of high-quality and uniform graphene films on copper foils,” Science, vol. 324, pp. 1312-1314, 2009. 21. Wang, X., Zhang, L., Weber, P. K., Wang, H. and Guo, J., “N-Doping of graphene through electrothermal reactions with ammonia,” Science, vol. 324, pp. 768-771, 2009. 22. Wu, C. X., Dong, G. F. and Guan, I. H., “Production of graphene sheets by a simple helium arcdischarge,” Physica E, vol. 42, no. 5, pp. 1267-1271, 2010. 23. Dan, L., Muller, M. B., Gilje, S., Kaner, R. B. and Wallance, G. G., “Processable aqueous dispersions of graphene nanosheets,” Nature Nanotechnology, vol. 3, pp. 101-105, 2008.

三維的單層奈米碳管經過酸處理後,可得到類似石墨烯的二維平面晶體,本論文使用化學方式製備的石墨烯及酸處理單層奈米碳管,以逐層靜電吸附自我組裝(Layer-by-Layer, LBL)製程成膜,再以浸泡硝酸及加熱處理得到最佳化的導電性薄膜。


Grapheneand carbon nanotubes are the emerging reinforcement materials which haveexcellentmechanical properties and high strength, toughness, hardness, head conductivity and electric conductivity. Because of wide range of applications, in this study, we exploit the electric conductivity discussion of the conductive thin film.

Thethree dimensions Single-walled Carbon Nanotubes (SWNTs) after acid treatment could be get a similar two-dimensional crystals of grephene. In this thesis,the conductive thin filmsof graphene by chemical method and SWNTs by acid treatmenthave coated throughLayer-by Layer process. Thin films were doped in the glass substrate through immersion acid and heat process to get the optimizing conductive.

To exploit the thin film formation process coulbd be controlled by LBL method,soselectedthe difference of graphene and SWNTs films by LBL to get the optimal parameters after optimized process,and then compared the correlation between the transmittance and sheet resistance.
其他識別: U0005-2108201313233100
Appears in Collections:精密工程研究所

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