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標題: Influence of inorganic anion on Cr(VI) photo-reduction in the presence of ferric ion
作者: Tzou, Y.M.
Hsu, C.L.
Chen, C.C.
Chen, J.H.
Wu, J.J.
Tseng, K.J.
關鍵字: photolytic reaction;Fe-Cl complex;inorganic anion;chromium(vi) reduction;hexavalent chromium;aqueous-solutions;hydrogen-sulfide;iron(iii);acid;photochemistry;kinetics;nitrate;fe(ii)
Project: Journal of Hazardous Materials
期刊/報告no:: Journal of Hazardous Materials, Volume 156, Issue 1-3, Page(s) 374-380.
Photo-reduction of Cr(VI) in a solution with single or multi-inorganic anions was evaluated. The results show that 38.5 mu M Cr(VI) is photo-reduced in the presence of NO3(-) at pH 1. The photolysis of NO3-, producing NO, or H2O2, may contribute to Cr(VI) reduction. The addition of 0.001-0.1 M chlorite to NO3(-) enhanced Cr(VI) photo-reduction when 35.8 mu M Fe(III) was present. This enhancement was the combinative result of photolysis of NO3- and Fe-Cl complexes, leading to the formation of NO2- and Fe(II), respectively, for Cr(VI) reduction. On the contrary, a significant decrease in Cr(VI) photo-reduction was observed with the addition Of PO43- and SO42-. This decrease was due to their strong competition with Fe(III) from Cl-, resulting in a marked decrease in the concentrations of Fe-Cl complexes. The results suggest that a direct irradiation of acidic wastewaters containing Cl-, NO3-, and Fe(III) is a feasible strategy for eliminating Cr(VI). (C) 2007 Elsevier B.V. All rights reserved.
ISSN: 0304-3894
DOI: 10.1016/j.jhazmat.2007.12.028
Appears in Collections:土壤環境科學系

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