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|標題:||Catalytic treating of gas pollutants over cobalt catalyst supported on porous carbons derived from rice husk and carbon nanotube||作者:||Lu, C.Y.
|關鍵字:||Porous carbon;Carbon nanotube;Carbonization;Catalyst;mesoporous activated carbon;chemical activation;porosity development;size distribution;adsorption;reduction;no;steam;zncl2;oxide||Project:||Applied Catalysis B-Environmental||期刊/報告no：:||Applied Catalysis B-Environmental, Volume 90, Issue 3-4, Page(s) 652-661.||摘要:||
Porous carbons were prepared from rice husks, commercial coconut-shell-derived carbon, and carbon nanotube (CNT) by activation with CO(2), KOH, and ZnCl(2). Cobalt catalysts were supported on the six different porous carbons by excess-solution impregnation, and were used to carry out reactions with different constituents such as NO + CO, toluene, NO + toluene, and NO + CO + toluene in the presence of 6% O(2) at 250 T to evaluate the activity of porous catalysts. The properties of the catalysts were analyzed by X-ray powder diffractometer (XRD), a field-emission scanning electron microscope (FESEM), transmission electron microscope (TEM), and an X-ray energy dispersive spectrometer (EDS). The cobalt catalysts supported on rice-husk-based carbon activated by CO(2) and those on commercial-activated-carbon re-treated by KOH showed 100% conversion on toluene oxidation. CNT-cobalt catalyst showed 63% NO conversion with CO and 46% with toluene at 250 degrees C. Among the six porous supported catalysts, the cobalt catalysts prepared with CNT and rice-husk-derived carbon by using CO(2) showed the best catalytic activity and thermal stability when compared to the others. (C) 2009 Elsevier B.V. All rights reserved.
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