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標題: Fabrication and characterization of poly(phenylene oxide)/SBA-15/carbon molecule sieve multilayer mixed matrix membrane for gas separation
作者: Weng, T.H.
Tseng, H.H.
Wey, M.Y.
關鍵字: Gas permeability;Poly(phenylene oxide);Zeolite;Mixed matrix membrane;H(2);nanocomposite membranes;hydrogen separation;composite membranes;permeation;performance;polymers;nanoparticles;size
Project: International Journal of Hydrogen Energy
期刊/報告no:: International Journal of Hydrogen Energy, Volume 35, Issue 13, Page(s) 6971-6983.
A novel multilayer mixed matrix membrane (MMM), consisting of poly(phenylene oxide) (PPO), large-pore mesoporous silica molecular sieve zeolite SBA-15, and a carbon molecular sieve (CMS)/Al(2)O(3) substrate, was successfully fabricated using the procedure outlined in this paper. The membranes were cast by spin coating and exposed to different gases for the purpose of determining and comparing the permeability and selectivity of PPO/SBA-15 membranes to H(2), CO(2), N(2), and CH(4). PPO/SBA-15/CMS/Al(2)O(3) MMMs with different loading weights of zeolite SBA-15 were also studied. This new class of PPO/SBA-15/CMS/Al(2)O(3) multilayer MMMs showed higher levels of gas permeability compared to PPO/SBA-15 membranes. The permselectivity of H(2)/N(2) and H(2)/CH(4) combinations increased remarkably, with values at 38.9 and 50.9, respectively, at 10 wt% zeolite loading. Field emission scanning electron microscopy results showed that the interface between the polymer and the zeolite in MMMs was better at a 10 wt% loading than other loading levels. The increments of the glass transition temperature of MMMs with zeolite confirm that zeolite causes polymer chains to become rigid. (C) 2010 Professor T. Nejat Veziroglu. Published by Elsevier Ltd. All rights reserved.
ISSN: 0360-3199
DOI: 10.1016/j.ijhydene.2010.04.024
Appears in Collections:環境工程學系所

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