Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/4990
DC FieldValueLanguage
dc.contributor章日行zh_TW
dc.contributor梁振儒zh_TW
dc.contributor.advisor廖文彬zh_TW
dc.contributor.author鄭佩珊zh_TW
dc.contributor.authorCheng, Pei-Shanen_US
dc.contributor.other中興大學zh_TW
dc.date2012zh_TW
dc.date.accessioned2014-06-06T06:33:44Z-
dc.date.available2014-06-06T06:33:44Z-
dc.identifierU0005-1507201111034800zh_TW
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T., 2010. Degadation of phenol using low concentration of ferric ions by the photo-Fenton process. Journal of Taiwan Institute of Chemical Engineers, pages 6. Kang, S. F., Liao, C. H. and Hung, H. P., 1999. Peroxidation treatment of dye manufacturing wastewater in the presence of ultraviolet light and ferrous ions. Journal of Hazardous Materials 65, 317-333. Konyushenko, E. N., Stejskal, J., Trchova, M., Hradil, J., Kovarova, J., Prokes, J., Cieslar, M., Hwang, J., Chen, K. H. and Sapurina, I., 2006. Multi-wall carbon nanotubes coated with polyaniline. Polymer 47, 5715-5723. Kuo, W. G., 1992. Decolorizing dye wastewater with Fenton’sreagent. Water Res. 26, 881-886. Kuo, W. S. and Wu, L. N., 2010. Fenton degradation of 4-chlorophenol contaminated water promoted by solar irradiation. Solar Energy 84, 59-65. Lucas, M. S. and Peres, J. A., 2006. Decolorization of the azo dye Rective Black 5 by Fenton and photo-Fenton oxidation. Dyes and Pigments 71, 236-244. 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Preparation and properties of the polymide/multi-walled carbon nanotubes (MWNTs)nanocomposites., Composites Science and Technology 66, 548-554zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/4990-
dc.description.abstract高級氧化程序在氧化過程中能夠提供一高活性、非特定的氫氧自由基(OH·),其具有強大之氧化力,能針對廢水中各種有機污染物進行分解。本研究使用Electro-Fenton程序處理雙偶氮染料(Reactive Black 5, RB5)廢水,配合適當參數,探討其礦化作用及色度去除能力,系統分別以不銹鋼及氧化銥為陰陽兩電極之材料,陰極處藉由曝氣產生溶氧,並於通電後還原生成過氧化氫,於操作中控制鐵的添加量,利用陰極之還原能力產生足夠的亞鐵離子,以減少反應催化劑的添加且減少鐵污泥的產生。 由背景實驗結果可知,本實驗之過氧化氫生成最佳操作參數為電流密度0.83 mA/cm2、空氣曝氣量1 NL/min,在此條件下操作3小時其最大過氧化氫生成累積量為18.05 mg/L,以此參數延長時間操作至6小時,過氧化氫生成累積量隨時間遞減,推測是因為本實驗所使用槽體為未分離式電解槽,可能會造成陰極所產生之過氧化氫於相對電極上反應而降解。 研究結果顯示,以Electro-Fenton程序處理染料(RB5)180分鐘後其色度、COD及TOC去除率分別為94.6、33.3、19.7%;延長時間處理也有提升其處理效能,相較於傳統Fenton程序,COD去除率和礦化率都有提高。 由FTIR分析結果可得,Electro-Fenton程序在處理染料180分鐘後其N=N鍵已經完全消失,且助色團之吸收隨著處理時間增加也有降低,表示染料已成功被脫色。 以Electro-Fenton程序處理RB5染料廢水,經反應180分鐘後,其脫色率接近100%、礦化率為19.7%;且反應符合擬一階動力模式。比起Fenton程序,以環境友善度來說,E-Fenton程序較有優勢。zh_TW
dc.description.abstractAdvanced Oxidation Process can provide highly activities, non-specific hydroxyl radical (HO·) in the oxidation. It has strong oxidation ability which can decompose a variety of organic pollutants in the wastewater. In this study, treating the Reactive black 5 (RB5) wastewater by Electro-Fenton process with the appropriate parameters to explore the mineralization and color removal capacity. The material of cathode and anode were stainless steel and iridium oxide using in the system. H2O2 can be electro-generated by reduction of oxygen and control the ferrous ion doses in the operation. The ferrous ions can reduce the catalyst addition and production of iron sludge which can generate by using the cathode reduction. Based on the results of background experiment, the optimal parameters for electro-generate H2O2 was at electric density of 0.83 mA/cm2 and air flow of 1 NL/min. Under these conditions, the maximum accumulation of H2O2 was 18.05 mg/L in 3 hours of operation. The accumulation of H2O2 was decreasing by time with extends treatment time to 6 hours in the same conditions. The results could be caused by the undivided cell tank in this experiment that cause H2O2 degrade in the relative electrode. Results show that the Electro-Fenton process deals with RB5 after 180 min. The color, COD and TOC removal rate were 94.6, 33.3, and 19.7% separately. Lengthening time can enhance the removal efficiency. Compare with traditional Fenton process, the COD removal efficiency and mineralization rate has increased.The result of FTIR analysis, Electro-Fenton process in the treatment of dye its N = N bond has completely disappeared after 180 min, and the absorption of chromophore increased with the treatment time has decreased, Indicate the dye has been successfully decolorization. The results obtained under the optimal operational parameters showed that decolorization (94.6%) and mineralization (approximately19.7%) of Reactive black 5 azo-dye have been achieved by electro-Fenton for 180 min. The rate of the oxidation reaction of RB5 azo-dye by electro-generated Fenton's reagent has been found to fit pseudo first-order kinetics.Compared to Fenton process; Electro-Fenton process has more advantages for environmentally-friendly.en_US
dc.description.tableofcontents誌謝………………………………………………………………………I 摘要………………………………………………………………………II Abstract.................................................III 目錄………………………………………………………………………V 第一章 前言................................................1 1-1研究緣起................................................1 1-2研究目的................................................1 第二章 文獻回顧............................................3 2-1台灣染整業現況..........................................3 2-2染料性質與相關研究......................................4 2-2-1染料廢水特性..........................................4 2-2-2染料結構..............................................5 2-2-3 偶氮染料之危害.......................................9 2-2-4 染整廢水放流標準....................................11 2-3 高級氧化程序..........................................13 2-3-1 芬頓程序............................................13 2-3-2 芬頓程序之影響因子..................................15 2-3-3 芬頓程序之優缺點....................................18 2-3-4 芬頓程序之相關文獻..................................20 2-4 電芬頓程序............................................22 2-4-1 電解作用............................................22 2-4-2 電芬頓原理..........................................22 2-4-3 電芬頓程序之影響因子................................28 2-4-4 電芬頓之相關文獻....................................32 第三章 材料與方法.........................................35 3-1 實驗設計..............................................35 3-2實驗操作方法...........................................38 3-2-1 系統控制參數........................................39 3-3 系統裝置..............................................44 3-4實驗藥品及配製.........................................46 3-4-1 實驗藥品............................................46 3-4-2 實驗藥品配製........................................47 3-5 實驗設備..............................................48 3-6 實驗分析方法..........................................49 第四章 結果與討論.........................................53 4-1 基礎實驗..............................................53 4-1-1 檢量線建立..........................................53 4-2 染料全波長分析........................................53 4-3 背景實驗..............................................56 4-3-1 H2O2生成實驗........................................56 4-3-2 直接電解............................................64 4-4 尋找Electro-Fenton最佳參數............................67 4-4-1不同pH值.............................................67 4-4-2 不同亞鐵劑量........................................70 4-5 不同操作程序..........................................73 4-5-1 芬頓程序............................................73 4-5-2 電芬頓程序..........................................76 4-6 延長操作時間..........................................80 4-6-1亞鐵離子添加程序.....................................84 4-7 降解動力分析..........................................86 4-7-1 反應速率定律........................................86 4-7-2 動力式的型態........................................86 4-8 中間產物探討..........................................89 4-8-1官能基分析...........................................89 4-9 成本控制評估..........................................93 第五章 結論與建議.........................................95 5-1結論...................................................95 5-2建議...................................................96 第六章 參考文獻...........................................97 中文部份..................................................97 西文部份..................................................99 附錄…………………………………………………………………….104 附錄表1-1................................................104 附錄表1-2................................................105 附錄表1-3................................................106 附錄表1-4................................................107zh_TW
dc.language.isoen_USzh_TW
dc.publisher環境工程學系所zh_TW
dc.relation.urihttp://www.airitilibrary.com/Publication/alDetailedMesh1?DocID=U0005-1507201111034800en_US
dc.subjectElectro-Fenton processen_US
dc.subject電芬頓程序zh_TW
dc.subjectdye wastewateren_US
dc.subjectmineralizationen_US
dc.subjectwater treatmenten_US
dc.subjectElectrogeneration hydrogen peroxideen_US
dc.subject染整廢水zh_TW
dc.subject礦化作用zh_TW
dc.subject廢水處理zh_TW
dc.subject電生成過氧化氫zh_TW
dc.title應用電化學合成過氧化氫處理染料廢水(RB5) 之研究zh_TW
dc.titleApplication of Electro-generated Hydrogen peroxide on the treatment of (RB5) dye wastewateren_US
dc.typeThesis and Dissertationzh_TW
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.openairetypeThesis and Dissertation-
item.cerifentitytypePublications-
item.fulltextno fulltext-
item.languageiso639-1en_US-
item.grantfulltextnone-
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