Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/5105
標題: 對苯二甲酸(PTA)製程廢水厭氧處理之研究
Anerobic Degradation of Terephthalate-containing Wastewater
作者: 王振家
Wang, Cheng-Chia
關鍵字: Purified terephthalic acid;純化對苯二甲酸(PTA) Purified Terephthalic acid;Benzoic acid;4-methylbenzoic acid;Anaerobic biodegration.;苯甲酸(BA) Benzoic acid;對甲基苯甲酸(4 CBA) 4-methylbenzoic acid;厭氧分解 anaerobic biodegradation
出版社: 環境工程學系所
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摘要: 
本研究以chemostat裝置植種取自宜蘭酒廠厭氧消化槽內之污泥,進行馴養及培養苯環類分解菌,採用蔗糖及乙酸鈉為人工合成溶液做為厭氧微生物生長所需之主要碳源(carbon source)及能量來源(energy source)。第一階段對苯二甲酸(TA)濃度由20 mg/L逐步調高至200 mg/L,操作期間11.5個月,TA穩定維持60~85﹪去除率。第二階段對苯二甲酸濃度每次增加50 mg/L,並提高至600 mg/L,操作3個月,TA亦穩定維持70~85﹪去除率,緊接著由批次瓶試驗評估結果,再將chemostat裝置進流水中基質對苯二甲酸濃度提高至950 mg/L,而同時間批次瓶實際製程廢水評估結果:B廠調合槽廢水,第38天TA去除率85﹪,所以得到結論判定:先用蔗糖及乙酸鈉馴養足夠的甲烷菌,再漸進式的引入PTA製程廢水即可馴養苯環類化合物之分解菌,而得到降解效果。
B廠製程廢水由逐步至全部取代人工合成廢水,進行chemostat連續流培養,結果顯示:B廠PTA製程廢水進流,TA /1,149 mg/L及COD/3,345 mg/L,出流水TA去除率88﹪及COD去除率70﹪,而達到預期研究目標。

Anaerobic sludge from a anaerobic digestor was seeded into the chemostat﹐into which acetate﹐PTA and benzene. were fed to be used as carbon and energy sources. During the acclimation stage﹐influent PTA concentration was gradually increased from 20 to 200 mg/L﹐During the acclimation stage﹐PTA removal was about 60~85﹪. when the system reached a stable state for the PTA removal. Influent PTA concentration was ﹐then﹐increased to 600 mg/L . After about three months of operation﹐PTA removal was 70~85﹪.
When the chemostat system reached stable state ﹐a realsystem wastewater to replace the articial wastewater. During this period ﹐the influent contained 1149 mg/L of PTA (3345 mg-COD/L). After 3 days of operation. COD and PTA Removals were about 70 and 88﹪﹐ respectively.
URI: http://hdl.handle.net/11455/5105
其他識別: U0005-0408200615114400
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