Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/5699
標題: 台中都會區大氣懸浮微粒長期觀測之研究
Long-term observation of ambient particulate matters in Taichung urban area
作者: 王曉玲
Wang, Hsiao-Ling
關鍵字: secondary aerosols;二次氣膠;agricultural waste burning;Asian dust storm;農廢燃燒;沙塵暴
出版社: 環境工程學系所
引用: 1. Allen, A. G., A. A. Cardoso, and G. O. Rocha, “Influence of Sugar Cane Burning on Aerosol Soluble Ion Composition in Southeastern Brazil,” Atmospheric Environment, Vol. 38, pp. 5025-5038 (2004). 2. Bourotte, C., A. P. Curi-Amarante, M. C. Forti, L. A. A. Pereira, A. L. Braga and P. A. Lotufo, “Association between Ionic Composition of Fine and Coarse Aerosol Soluble Fraction and Peak Expiratory Flow of Asthmatic Patients in São Paulo City (Brazil),” Atmospheric Environment, Vol. 41, 2036-2048 (2007). 3. Chen, S. J., L. T. Hsieh, M. J. Kao, W. Y. Lin, K. L. Huang, and C. C. Lin, “Characteristics of Particles Sampling in Southern Taiwan During the Asian Dust Storm Periods in 2000 and 2001,” Atmospheric Environment, Vol. 38, pp. 5925-5934 (2004). 4. Cheng, M. T., Y. C. Lin, C. P. Chio, C. F. Wang, and C. Y. Kuo, “Characteristics of Aerosols Collected in Central Taiwan During an Asian Dust Event in Spring 2000,” Atmospheric Environment, Vol. 61, pp. 1439-1450 (2005). 5. Cheng, M. T., C. L. Horng, Y. R. Su, L. K. Lin, Y. C. Lin and C. C. K. Chou, “Particulate Matter Characteristics during Agricultural Waste Burning in Taichung City, Taiwan,” Journal of Hazardous Materials, Vol. 165, No. 1-3, pp. 187-192 (2009a). 6. Cheng, M. T., W. C. Chou, C. P. Chio, S. C. Hsu, Y. R. Su, P. H. Kuo, B. J. Tsuang, S. H. Lin and C. C. K. Chou, “Compositions and Source Apportionments of Atmospheric Aerosol during Asian Dust Storm and Local Pollution in Central Taiwan,” Journal of Atmospheric Chemistry (2009b). 7. Chio, C. P., M. T. Cheng and Wang, C. F., “Source Apportionment to PM10 in Different Air Quality Conditions for Taichung Urban and Costal Areas, Taiwan,” Atmospheric Environment, Vol. 38, pp. 6893-6905 (2004). 8. Chou, C. C. K., C. Y. Lin, T. Z. Chen, S. C. Hsu, S. C. Lung, S. C. Liu and C. Y. Young, “Influence of Long-range Transport Dust Particles on Local Air Quality: A Case Study on Asian Dust Episodes in Taipei during the Spring of 2002,” Terrestrial Atmospheric Oceanic Sciences, Vol. 15, pp. 881-889 (2004). 9. Chou, C. C. K., S. H. Huang, T. K. Chen, C. Y. Lin, and L. C. Wang, “Size-Segregated Characterization of Atmospheric Aerosols in Taipei During Asian Outflow Episodes,” Atmospheric Research, Vol. 75, pp. 89-109 (2005). 10. Engling, G., J. J. Lee, Y. W. Tsai, S. C. Lung, C. K. Chou, and C. Y. Chan,“Size-Resolved Anhydrosugar Composition in Smoke Aerosol from Contralled Field Burning of Rice Straw,”Aerosol Science and Technology, Vol. 43, pp. 662-672 (2009). 11. Ezcurra, A., I. O. Zárate, P. V. Dhin, and J. P. Lacaux, “Cereal Waste Burning Pollution Observed in the Town of Vitoria (North Spain),” Atmospheric Environment, Vol. 35, pp. 1377-1386 (2001). 12. Fang, G. C., C. N. Chang, Y. S. Wu, S. C. Lu, P. P. C. Fu, S. C. Chang, C. D. Cheng, and W. H. Yuen, “Concentration of Atmospheric Particulates During a Dust Storm Period in Central Taiwan, Taichung,” the Science of the Total Environment, Vol. 287, pp. 141-145 (2002). 13. Fang, G. C., Y. S. Wu, J. C. Chen, J. Y. Rau, S. H. Huang and C. K. Lin, “Concentrations of Ambient Air Particulates (TSP, PM2.5 and PM2.5-10) and Ionic Species at Offshore Areas Near Taiwan Strait,” Journal of Hazardous Materials, Vol. B132, pp. 269-276 (2006). 14. Gray, H. A., G. R. Cass, J. J. Huntzicker, E. K. Heyerdahl, J. A. Rau, “Characterisitics of Atmospherics Organic and Elemental Carbon Particle Concentrations in Los Angeles, ”. Environment Science and Technology, Vol. 20, pp. 580-589 (1986). 15. Kerminen, V. M., Ojanen, C., Pakkanen, T., Hillamo, R., Aurela, M., Meriläinen, J., “Low-molecular-weight dicarboxylic acid in an urban and rural atmosphere,”. Journal of Aerosol Science 31, Vol. pp. 349-362. (2000) 16. Kim, B. G., and S. U. Park., “Transport and Evolution of a Winter-time Yellow Send Observed in Korea,” Atmospheric Research, Vol. 35, pp. 3191-3201 (2001). 17. Kuo, C. Y., P. T. Chen, Y. C. Lin, C. Y. Lin, H. H. Chen and J. F. Shih, “Factors Affecting the Concentrations of PM10 in Central Taiwan,” Chemosphere, Vol. 70, No. 7, pp. 1273-1279 (2008). 18. Lin, J. J., “Characterization of Water-soluble Ion Species in Urban Ambient Particles,” Environmental International, Vol. 28, pp. 55-61 (2002). 19. Lonati, G., Giugliano, M., Butelli, P., Romele, L., Tardivo, R., 2005. Major chemical components of PM2.5 in Milan (Italy). Atmospheric Environment, Vol. 39, pp. 1925-1934. 20. Parmar, R. S., G. S. Satsangi, M. Kumari, A. Lakhani, S. S. Srivastava, and S. Prakash, “Study of Size Distribution of Atmospheric Aerosol at Agra”, Atmospheric Environment, Vol. 35, pp. 693-702 (2001). 21. Seinfeld, J. H. and S. N. Pandis, Atmospheric Chemistry and Physics from Air Pollution to Climate Change, John Wiley & Sons, Inc, New York (1998). 22. Tsai, Y. I. and C. L. Chen, “Characterization of Asian Dust Storm and Non-Asian Dust Storm PM2.5 Aerosol in Southern Taiwan,” Atmospheric Environment, Vol. 40, pp. 4734-4750 (2006). 23. Tsai, Y. I. and M. T. Cheng, “Characterization of Chemical Species in Atmospheric Aerosols in a Metropolitan Basin,” Chemosphere, Vol. 54, pp. 1171-1181 (2004). 24. Tuomo, A. P.,L. Kati, K. H.Christina, A. T. Timo, E. H. Risto, K. Tarja, K. Aun, M. Willy, “Sources and Chemical Composition of Atmosphere Fine and Coarse Particles in Helsinki Area,” Atmospheric Environment, Vol. 35, pp. 5381-5391 (2001). 25. Wang, C. C., C. T. Lee, S. C. Liu, and J. P. Chen, “Aerosol Characterization at Taiwan''s Northern Tip During Ace-Asia,” TAO, Vol. 15, No.5, pp. 839-855 (2004). 26. Yang, H. H., C. H. Tsai, M. R. Chao, Y. L. Su, and S. M. Chien, “Source Identification and Size Distribution of Atmospheric Polycyclic Aromatic Hydrocarbons During Rice Straw Burning Period,” Atmospheric Environment, Vol.40, pp. 1266-1274 (2006). 27. Yao, X., A. P. S. Lau, M. Fang, C. K. Chen, and M. Hu, “Size Distributions and Formation of Ionic Species in Atmospheric Particulate Pollutants in Beijing, China: 1-Inorganic Ions,” Atmospheric Environment, Vol. 37, pp. 2991-3000 (2003). 28. Yuan, C. S., C. C. San, M. C. Chen, M. H. Huang, S. W. Chang, Y. C. Lin, and C. G. Lee, “Mass Concentration and Size-resolved Chemical Composition of Atmospheric Aerosols Sampled at the Pescadores Island during Asian Dust Storm Periods in the Years of 2001 snd 2002,”Terrestrial Atnospheric Oceanic Sciences,Vol. 15, pp. 857-879 29. 林銳敏、蔡俊鴻、江鴻龍、林允涵、張凱倫,「二次氣膠粒徑分佈變異特性研究」,第十屆氣膠科技研討會,台中,2003。 30. 劉乙琦,袁中新,蔡協宏,覃偉民,「沙塵暴期間懸浮微粒與沙源地之灰關聯分析」,2008年第十五屆國際氣膠科技研討會論文集,台北,台灣,第36頁(2008)。 31. 黃淑雍,龍世俊,劉純湖,溫子瑤,傅琪,劉紹臣,「2005~2007年台北地區水溶性離子濃度之變化」,2008年第十五屆國際氣膠科技研討會論文集,台北,台灣,第28頁(2008)。 32. 李崇垓,袁中新,劉乙琦,林坤信,「大陸沙塵暴對台灣澎湖地區大氣氣膠特徵之影響」, 2006年海峽兩岸環境保護協會研討會論文集,高雄,台灣,第47-51頁( 2006)。 33. 張小玲,宋敏紅,錢正安,徐敬,石少宏,云靜波,「2006年春季中蒙中、東區沙塵暴低層環流及變化初步分析」,2006年海峽兩岸環境保護協會研討會論文集,高雄,台灣,第77-83頁( 2006)。 34. 鄭曼婷,蘇怡如,林煜棋,林立凱,「大陸沙塵暴對台中都會區大氣懸浮微粒物化特性之影響分析」, 2006年海峽兩岸環境保護協會研討會論文集,台中,台灣,第33-39頁( 2006)。 35. 朱宏勳、李崇德、劉紹臣,沈士翔,「長程傳輸對北台灣大氣氣膠特性的影響」,第十一屆中華民國國際氣膠科技研討會論文專輯,台南 ( 2004)。 36. 盧信忠、謝仁傑、沈銘祥,「台中地區高PM10濃度值之分布特性」,第十九屆空氣污染控制技術研討會論文專輯,台北 (2002)。 37. 李蔚德,「大陸沙塵事件與農廢燃燒事件之大氣懸浮微粒的粒徑分佈及特性分析」,碩士論文,國立中興大學環境工程學系,台中( 2004)。 38. 袁中新、邵承宗、陳敏宗、黃明和,「非沙塵暴期間澎湖群島氣膠微粒之物化特性探討」,第十一屆中華民國國際氣膠科技研討會論文專輯,台南( 2004) 39. 鄭曼婷,丁偉諭,李蔚德,蘇怡如,「農廢燃燒期間空氣污染物的化學組成和粒徑分佈」,第二十屆空氣污染控制技術研討會論文專輯,pp. 3-73,(2003)。 40. 洪春量,「中台灣PM2.5和酸鹼性氣體特性及二氧化硫轉化率之研究」,博士論文,國立中興大學環境工程學系,台中( 2008)。 41. 何燕婷,「中臺灣長期觀測亞洲沙塵暴的研究」,碩士論文,國立中興大學環境工程學系,台中( 2007)。 42. 林煜棋,「大氣酸性氣體與氣膠的特性和其影響因子分析」,博士論文,博士論文,國立中興大學環境工程學系,台中( 2006)。 43. 蘇怡如,「台中都會區大氣懸浮微粒特性及農廢燃燒與沙塵暴的案例分析」,碩士論文,國立中興大學環境工程學系,台中( 2006)。 44. 林立凱,「台中都會區PM10 高污染事件大氣懸浮微粒之物化特性」,碩士論文,國立中興大學環境工程學系,台中( 2005)。 45. 李蔚德,「大陸沙塵事件和農廢燃燒事件之大氣懸浮微粒的粒徑分佈及特性分析」,碩士論文,國立中興大學環境工程學系,台中 (2004)。 46. 王景良,「中部空品區污染源逸散粉塵的組成分析」,碩士論文,國立中興大學環境工程學系,台中(2000)。 47. 柳中明,「大陸沙塵抵台對台灣空氣品質的影響與分區分級制度的訂定」,環保署,監資處,台北(2004)。 48. 行政院環保署網站。
摘要: 
大氣懸浮微粒主要源自自然排放及人為污染排放,其化學組成和粒徑分佈影響能見度、氣候及民眾的健康,因此本研究於2002 ~ 2008年期間以雙粒徑分道採樣器採集台中都會區之懸浮微粒樣本,並分析其成份,以瞭解空氣污染特性與其來源。
研究結果顯示,PM10年均值為63.9 ± 31.0 μg m-3,其中PM2.5/ PM10比值為0.64,並以SO42-、NO3-以及NH4+所佔比例最高,顯示大氣懸浮微粒以細微粒及二次氣膠的生成貢獻為主。在事件日的分析上,4次農廢燃燒事件期間,PM2.5中的Cl-、K+、NO3-、OC及EC為重要特徵污染物,並分別為非事件的10.3、6.4倍、4.7、4.2和3.2倍。此外,11次的沙塵暴事件日中,PM2.5-10質量濃度為非事件日之2.0 ~ 3.3倍,且海鹽飛沫的Na+、Cl-和地殼物質中的Mg2+及Ca2+依序為非事件日的0.7 ~ 3.2倍、1.1 ~ 5.1倍、1.0 ~ 3.6倍及1.0 ~ 5.2倍,故沙塵事件期間,粗粒、海鹽和地殼元素為主要的量測指標,最後總結量測結果,可知農廢燃燒和沙塵為造成懸浮微粒高污染事件的主因,平日則以衍生性氣膠為主要貢獻源。

Atmospheric particulates were mainly derived from natural and anthropogenic emission sources. The chemical compositions and size distributions of particulate matters can affect visibility, climate and human health . Therefore in this study, aerosol samples were collected by using dichotomous samplers from 2002 to 2008 in Taichung urban area. The samplers were then further analyzed to determine the chemical compositions in order to investigate the characteristics and sources of particulates.
The results of this study showed that annual mean concentration of PM10 was 63.9 ± 31.0 μg m-3. The ratio of PM2.5/PM10 was 0.64. SO42-, NO3- and NH4+, were the major species of the particulates which indicated that the ambient particulates were dominated by fine particles and secondary aerosols. During the sampling period, there were 4 agricultural waste burning events. During these events, Cl-, K+, NO3-, OC and EC in PM2.5 were the important marking pollutants. Their concentrations were 10.3 , 6.4 , 4.7 , 4.2 and 3.2 times higher as compared to those in the normal days. Furthermore, there were totally 11 Asian dust storm events. In these events, the concentrations of PM2.5-10 were 2.0 ~ 3.3 times higher than the non-dust storm periods. Sea-salt species Na+ , Cl- and crustal species Mg2+ and Ca2+ were 0.7 ~ 3.2 , 1.1 ~ 5.1 , 1.0 ~ 3.6 and 1.0 ~ 5.2 times higher as compared to those in the non-dust storm events. Therefore the major increased contents in the dust-storm events were coarse particle, sea salt and crustal element. In conclusion, agricultural waste burning and dust storm were the major causes for high pollution. But in normal days, the secondary aerosols were the major sources.
URI: http://hdl.handle.net/11455/5699
其他識別: U0005-1908200921463300
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