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標題: Bis{mu(2)-2- 2-(dimethylamino)ethyliminomethyl -phenolato} bis chlorozinc(II)
作者: Chen, H.Y.
Lin, C.C.
關鍵字: ring-opening polymerization;catalyst precursors;carbon-dioxide;zinc;alkoxides;complexes;lactide;ligands;single;initiators;magnesium
Project: Acta Crystallographica Section E-Structure Reports Online
期刊/報告no:: Acta Crystallographica Section E-Structure Reports Online, Volume 62, Page(s) M1693-M1694.
The title complex, [Zn-2(C11H15N2O)(2)Cl-2] or [LZnCl](2), where L is the 2-[2-(dimethylamino)ethyliminomethyl]phenolate anion, is obtained by the reaction of LZnEt with CDCl3 or by the reaction of LH with ZnCl2 in refluxing tetrahydrofuran. The Zn atoms in the dimeric complex are bridged by the O atoms of the phenolate anions, and the coordination geometry around each Zn atom is distorted square-based pyramidal. The two Cl atoms lie on the same side of the central Zn2O2 plane.
ISSN: 1600-5368
DOI: 10.1107/s1600536806024093
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