Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/68106
DC FieldValueLanguage
dc.contributor.authorWu, Y.H.en_US
dc.contributor.authorLin, G.L.en_US
dc.date2009zh_TW
dc.date.accessioned2014-06-11T05:56:16Z-
dc.date.available2014-06-11T05:56:16Z-
dc.identifier.issn0970-7077zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/68106-
dc.description.abstractA combined model for the structures of the mixed micelles of taurocholate and 1,2-ethylene-di-N-n-propylcarbamate (1) has been proposed. Present model suggests that the structures of micelles of taurocholate are equally composed of these four dimeric fragments. Moreover, lipid molecules can only insert into back-to-back dimeric fragments but not into face-to-face dimeric fragments in the mixed micelles of taurocholate and lipid. To test this model, a short-chain analogue of glycerol lipid, 1,2-ethylene-di-N-n-propylcarbamate (1), was synthesized and was mixed with the micellar taurocholate to form the mixed micelle of taurocholate and compound 1. From the H-1 NMR spectra. the cc-methylene protons of compound I split after formation of the mixed micelle with taurocholate. Thus, half of compound I molecules insert into the anti-parallel back-to-back dimer's in the mixed micelle and the other half of compound 1 molecules insert into the parallel back-to-back dimers in the mixed micelle.en_US
dc.language.isoen_USzh_TW
dc.relationAsian Journal of Chemistryen_US
dc.relation.ispartofseriesAsian Journal of Chemistry, Volume 21, Issue 9, Page(s) 6981-6992.en_US
dc.subjectNMRen_US
dc.subjectMixed Micelleen_US
dc.subjectTaurocholateen_US
dc.subjectLipid analogueen_US
dc.subjectpseudomonas-species lipaseen_US
dc.subjectbile-salt micellesen_US
dc.subjectsodium taurocholateen_US
dc.subjectself-associationen_US
dc.titleH-1 NMR Study of Mixed Micelles of Taurocholate and 1,2-Ethylene-di-N-n-propylcarbamateen_US
dc.typeJournal Articlezh_TW
item.languageiso639-1en_US-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.openairetypeJournal Article-
item.fulltextno fulltext-
item.grantfulltextnone-
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