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|標題:||Induced circular dichroism of stereoregular vinyl polymers||作者:||Chen, L.C.
|關鍵字:||helical polymers;chirality assignment;block-copolymers;optical-activity;alpha-olefins;amino group;induction;poly((4-carboxyphenyl)acetylene);superstructures;polymerization||Project:||Chemical Communications||期刊/報告no：:||Chemical Communications, Volume 48, Issue 30, Page(s) 3668-3670.||摘要:||
Stereoregular vinyl polymers, poly(2-vinyl pyridine)s (P2VPs), were synthesized to examine the tacticity effect on the induced circular dichroism (ICD) via association with chiral acids. The ICD was found to be strongly dependent on the isotacticity of the P2VPs and the acidity of chiral acid in addition to its bulkiness.
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