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標題: Al2O3-supported Cu-Co bimetallic catalysts prepared with polyol process for removal of BTEX and PAH in the incineration flue gas
作者: Lu, C.Y.
Tseng, H.H.
Wey, M.Y.
Liu, L.Y.
Kuo, J.H.
Chuang, K.H.
關鍵字: Polyol process;Volatile organic compounds;Oxidation;Incineration flue;gas;organic-compounds;oxidation;decomposition;oxide;metal;voc
Project: Fuel
期刊/報告no:: Fuel, Volume 88, Issue 2, Page(s) 340-347.
The polyol process is an effective method to generate well-dispersed nanoscale active sites on a support. To study the activity of catalysts prepared by polyol process, Cu1.25Co3.75/Al2O3, Cu2.5Co2.5/Al2O3, and Cu3.75Co1.25/Al2O3 were studied in a pilot-scale incinerator system to remove benzene, toluene, ethylbenzene, xylene, and polycyclic aromatic hydrocarbons, and the effect of lead in a flue gas was also discussed. The pilot-scale experiment results indicated that Cu1.25Co3.75/Al2O3 exhibited a good performance on organic compounds removal, without being poisoned by lead. The bimetal containing Cu/Co = 1/3 exhibits a better activity and stabilization on oxidation than the others. When the Cu/Co ratio was above one, the X-ray powder diffractometer, and Fourier transform infrared spectroscopy analyses results revealed that several components (Cu-0, CuO, and CuCo2O4) of the spent catalysts disappeared. This may be due to the active sites that were covered with an amount of CH3-groups. (C) 2008 Elsevier Ltd. All rights reserved.
ISSN: 0016-2361
DOI: 10.1016/j.fuel.2008.09.012
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