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標題: Preparation of a new cobalt-containing diphosphine ligand and its reaction towards dicobalt octacarbonyl; X-ray crystal structure of Co-2(CO)(4)(mu-CO)(2){mu-P,P-(mu-PPh2C CPPh2)Co-2(CO)(6)}
作者: Hong, F.E.
Huang, Y.C.
Wang, S.L.
Liao, F.L.
關鍵字: diphosphine ligand;alkyne-bridged dicobalt complexes;chelating ligand;tetranuclear complexes
Project: Inorganic Chemistry Communications
期刊/報告no:: Inorganic Chemistry Communications, Volume 2, Issue 10, Page(s) 450-452.
Consecutive reactions of bis(diphenylphosphino)acetylene with CO2(CO)(8) resulted in an alkyne-bridged, diphosphine-chelated tetracobalt complex, [Co-2(CO)(4)(mu-CO)(2){mu-P,P-(mu-PPh2C drop CPPh2)Co-2(CO)(6)}] (2), which has been characterized by spectroscopic means as well as X-ray studies. (C) 1999 Elsevier Science S.A. All rights reserved.
ISSN: 1387-7003
DOI: 10.1016/s1387-7003(99)00121-5
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