Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/69815
DC FieldValueLanguage
dc.contributor.authorYang, C.B.en_US
dc.contributor.authorTung, J.Y.en_US
dc.contributor.authorChen, J.H.en_US
dc.contributor.authorLiao, F.L.en_US
dc.contributor.authorWang, S.L.en_US
dc.contributor.authorWang, S.S.en_US
dc.contributor.authorHwang, L.P.en_US
dc.date1998zh_TW
dc.date.accessioned2014-06-11T05:58:57Z-
dc.date.available2014-06-11T05:58:57Z-
dc.identifier.issn1074-1542zh_TW
dc.identifier.urihttp://hdl.handle.net/11455/69815-
dc.description.abstractIn this work, we determine the crystal structure of dimethoxo(meso-tetra(4-methoxyphenylporphyrinato))tin(IV), Sn(tmpp)(OMe)(2) (1). Experimental results indicate that the tin atom has an octahedral geometry. The geometry around the tin center has Sn(1)-O(5) = 2.020(6), Sn(1)-O(6) = 2.003(7) Angstrom and an average Sn(1)-N = 2.10(1) Angstrom. The two methoxo groups are unidentately coordinated to the tin(IV) atom. Two-stage hydrolysis of Sn(tmpp)(OMe)(2) in CDCl3 was observed by H-1 and C-13 NMR spectroscopy. Compound (1) crystallizes in the space group P2(1)/n with a = 14.7492(1), b = 19.2022(3), c = 16.0806(2) Angstrom, beta = 94.104(1)degrees and Z = 4.en_US
dc.language.isoen_USzh_TW
dc.relationJournal of Chemical Crystallographyen_US
dc.relation.ispartofseriesJournal of Chemical Crystallography, Volume 28, Issue 6, Page(s) 481-486.en_US
dc.relation.urihttp://dx.doi.org/10.1023/a:1021776923873en_US
dc.subjectcrystal structureen_US
dc.subjecttin porphyrinen_US
dc.subjecttwo-stage hydrolysisen_US
dc.subjectmethanolateen_US
dc.subjecttrans equivalent axial liganden_US
dc.subjecttin(iv) porphyrin complexesen_US
dc.subjectmolecular-structureen_US
dc.subject2-step hydrolysisen_US
dc.titleCrystal structure and two-stage hydrolysis of dimethoxo(meso-tetra(4-methoxyphenylporphyrinato))tin(IV), Sn(tmpp)(OMe)(2)en_US
dc.typeJournal Articlezh_TW
dc.identifier.doi10.1023/a:1021776923873zh_TW
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextno fulltext-
item.cerifentitytypePublications-
item.grantfulltextnone-
item.languageiso639-1en_US-
item.openairetypeJournal Article-
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