Please use this identifier to cite or link to this item: http://hdl.handle.net/11455/70188
標題: Degradation efficiencies and mechanisms of the ZnO-mediated photocatalytic degradation of Basic Blue 11 under visible light irradiation
作者: Lu, C.S.
Wu, Y.T.
Mai, F.D.
Chung, W.S.
Wu, C.W.
Lin, W.Y.
Chen, C.C.
關鍵字: Dye;ZnO;Photocatalytic;Basic Blue 11;HPLC-PDA-MS;malachite green;leucomalachite green;methyl green;water;tio2;photodegradation;suspensions;catalysts;pathways;products
Project: Journal of Molecular Catalysis a-Chemical
期刊/報告no:: Journal of Molecular Catalysis a-Chemical, Volume 310, Issue 1-2, Page(s) 159-165.
摘要: 
A ZnO-mediated photocatalysis process was used to successfully degrade Basic Blue 11 (BB-11) under visible light irradiation. The effects of influential factors like initial dye concentration, catalyst dosage. and initial pH were studied. To obtain a better understanding the mechanistic details of ZnO-assisted photodegradation of the BB-11 dye with low watt visible light irradiation, a large number of the intermediates resulting from the photodegradation were separated, identified, and characterized by high-performance liquid chromatography-photodiode array-mass spectrometry (HPLC-PDA-MS) techniques. The results indicated that the N-de-alkylation and oxidative degradation of BB-11 dye took place and that N-hydroxyalkylated intermediates were generated during the process. From the same identified intermediates we got under UV or visible light irradiation, it is proposed that the major oxidant under visible light irradiation was (center dot)OH radical, not O(2)(-center dot). HPLC-PDA-MS analysis verified the identity of intermediates, and a reaction mechanism based on them was proposed. (C) 2009 Elsevier B.V. All rights reserved.
URI: http://hdl.handle.net/11455/70188
ISSN: 1381-1169
DOI: 10.1016/j.molcata.2009.06.011
Appears in Collections:期刊論文

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