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標題: Polarized Raman scattering in lanthanum gallogermanate glasses
作者: Hwa, L.G.
Shiau, J.G.
Szu, S.P.
關鍵字: aluminogermanate glasses;galliosilicate glasses;bao-ga2o3-geo2;glasses;gallosilicate glasses;germanate glasses;spectra;spectroscopy;silica;galliogermanate;crystalline
Project: Journal of Non-Crystalline Solids
期刊/報告no:: Journal of Non-Crystalline Solids, Volume 249, Issue 1, Page(s) 55-61.
Polarized Raman scattering has been used to characterize the structure of two series of lanthanum gallogermanate glasses with the composition xLa(2)O(3)-GeO2-0.25Ga(2)O(3) and 0.33La(2)O(3)-GeO2-yGa(2)O(3), where x, y = 0.2, 0.25, 0.33, and 0.5, We assigned the vibrational modes to different types of atomic motions in the glass network. No direct evidence of the six-fold coordinated (octahedral) germanium or gallium ions in the glass structure has been observed. The nature of the low frequency Raman peak - the so called Boson peak - is discussed in terms of the existing theories. (C) 1999 Elsevier Science B.V. All rights reserved.
ISSN: 0022-3093
DOI: 10.1016/s0022-3093(99)00300-2
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